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Charles T. Campbell

Representative Publications

Energetics of Adsorbed Methanol and Methoxy on Pt(111) by Microcalorimetry. Karp, E. M.; Silbaugh, T. L.; Crowe, M. C.; Campbell, C. T. J. Am. Chem. Soc. 2012, 134 (50), 20388–20395.

The Entropies of Adsorbed Molecules. Campbell, C. T.; Sellers, J. R. V. J. Am. Chem. Soc. 2012, 134 (43), 18109–18115.


Surface chemistry: Key to control and advance myriad technologies. Yates, J. T., Jr.; Campbell, C. T. Proc. Natl. Acad. Sci. USA 2011, 108, 911–916.


Adsorption Microcalorimetry: Recent Advances in Instrumentation and Application. Crowe, M. C.; Campbell, C. T. Annu. Rev. Anal. Chem. 2011, 4, 41–58.


The Energy of Adsorbed Hydroxyl on Pt(111) by Microcalorimetry. Lew, W.; Crowe, M. C.; Karp, E. M.; Lytken, O.; Farmer, J. A.; Árnadóttir, L.; Schoenbaum C.; Campbell, C. T. J. Phys. Chem. C 2011, 115, 11586–11594.


Insights into Catalysis by Gold Nanoparticles and their Support Effects through Surface Science Studies of Model Catalysts. Campbell, C. T.; Sharp, J. C.; Yao, Y. X.; Karp, E. M.; Silbaugh, T. L. Faraday Discuss. 2011, 152, 227–239. (Invited)


Towards Well-Defined Metal-Polymer Interfaces: Temperature-Controlled Suppression of Subsurface Diffusion and Reaction at the Calcium/Poly(3-Hexylthiophene) Interface. Bebensee, F.; Schmid, M.; Steinruck, H.-P.; Campbell, C. T.; Gottfried, J. M. J. Am. Chem. Soc. 2010, 132, 12163–12165.


Ceria Maintains Smaller Metal Catalyst Particles by Strong Metal - Support Bonding. Farmer, J. A.; Campbell, C. T. Science 2010, 329, 933–936.


Particle size dependent heats of adsorption of CO on supported Pd nanoparticles as measured with a single crystal microcalorimeter. J. H. Fischer-Wolfarth1, J. A. Farmer, J. M. Flores-Camacho1, A. Genest, I. V. Yudanov, N. Rösch, C. T. Campbell, S. Schauermann and H. J. Freund, Physical Review B (Rapid Communication) 81, 241416(R), 2010, 4 pages. (reprint)


The degree of rate control: how much the energies of intermediates and transition states control rates. C. Stegelmann, A. Andreasen, C. T. Campbell, J. Am. Chem. Soc. 2009, 131, 8077-8082. (Cover Article, highlighted in Science) (reprint)


Experimental measurements of the energetics of surface reactions. C. T. Campbell and O. Lytken, Surface Science 2009, 603, 1365-72. (reprint)


Formation of the calcium / poly(3-hexylthiophene) interface: structure and energetics. J. Zhu, F. Bebensee, W. Hieringer, W. Zhao, J. H. Baricuatro, J. A. Farmer, Y. Bai, H-P. Steinrück, J. M. Gottfried and C. T. Campbell, Journal of the American Chemical Society 2009, 131, 13498-507. (reprint)


Catalytic Reaction Energetics by Single Crystal Adsorption Calorimetry: Hydrocarbons on Pt(111). O. Lytken, W. Lew and C. T. Campbell, Chemical Society Reviews 2008, 37, 2172-2179. (Invited in honor of Ertl’s Nobel Prize) (reprint)


Ca Adsorption on MgO(100):  Energetics, Structure and Role of Defects. J. F. Zhu, J. A. Farmer, N. Ruzycki, L. Xu; C. T Campbell and G. Henkelman, Journal of the American Chemical Society 2008, 130, 2314-22.


Reactivity and sintering kinetics of Au / TiO2(110) model catalysts: particle size effects. S. C. Parker and C. T. Campbell, Topics in Catalysis 2007, 44, 3-13. (reprint)


SPR Microscopy and Its Applications to High-Throughput Analyses of Biomolecular Binding Events and Their Kinetics. C. T. Campbell and G. Kim, Biomaterials 2007, 28, 2380–2392. (reprint)


Heat of Adsorption of Naphthalene on Pt(111) Measured by Adsorption Calorimetry. J. Michael Gottfried, Ebbe K. Vestergaard, Parthasarathi Bera, and Charles T. Campbell, J. Phys. Chem. B 2006, 110, 17539-17545. (reprint)


A Demonstration of High-throughput Immunoassay and Small Molecule Binding on Protein Microarrays with SPR Microscopy. G. Kim, L. Jiang, P.K. Rathod, C.T. Campbell, A. Nishimoto and V. Casasanta, NSTI-Nanotech 2005 (Proc. 2005 Nano Science and Technology Institute Conference) Vol. 1, Chapter 7.2, 381-4, (2005).


Pd diffusion on MgO(100): the role of defects and small cluster mobility. L. Xu; G. Henkelman; C. T Campbell; H. Jonsson, Surface Sci. 2006, 600, 1351-62.


Thermodynamics of Statherin Adsorption onto Hydroxyapatite. R. Goobes, G. Goobes, C. T. Campbell and P. S. Stayton, Biochemistry 45, 5576-86 (2006). reprint


Transition metal oxides: extra thermodynamic stability as thin films. Charles T. Campbell, Physical Review Letters 96, 066106 (2006) 4 pages. reprint


Oxygen Vacancies and Catalysis on Ceria Surfaces (Perspective). Charles T. Campbell and Charles H. F. Peden, Science 309, 713-14 (2005).


Methane adsorption and dissociation and oxygen adsorption and reaction with CO on Pd nanoparticles on MgO(100) and on Pd(111). S. L. Tait, Z. Dohnálek, C. T. Campbell, B. D. Kay, Surface Sci. 591, 90-107, (2005). reprint


Heats of adsorption of Pb on pristine and electron-irradiated poly(methyl methacrylate) by microcalorimetry. S.F. Diaz, J.F. Zhu, J.J.W. Harris, P. Goetsch, L. Merte and C. T. Campbell, Surface Sci. 598, 22-34, (2005). reprint


n-Alkanes on MgO(100):  II. Chain Length-dependence of Kinetic Desorption Parameters for Small n-Alkanes. S. L. Tait, Z. Dohnálek, C. T. Campbell, B. D. Kay, J. Chem. Phys. 122, 164708, 2005 (13 pages). reprint


Toward tomorrow’s catalysts. C. T. Campbell, Nature (News and Views), 432, 282-3, (2004). reprint


Surface products and coverage dependence of dissociative ethane adsorption on Pt{110}-(1×2). J. J. W. Harris, V. Fiorin, C. T. Campbell and D. A. King, J. Phys. Chem. B 109, 4069-4075, (2005).


The active site in nanoparticle gold catalysis (A Perspective). C. T. Campbell, Science 306, 234-5, (2004).


Metal-carbon bond energies for adsorbed hydrocarbons from calorimetric data. H. Gross, C. T. Campbell and D. A. King, Surface Science 572, 179-190, (2004). reprint


A Calorimeter for Adsorption Energies of Large Molecules on Single Crystal Surfaces. H. M. Ajo, H. Ihm, David E. Moilanen and C. T. Campbell, Review of Scientific Instruments 75, 4471-80, (2004). reprint


Calorimetric Measurement of the Heat of Adsorption of Benzene on Pt(111). H. Ihm, H. M. Ajo, J. M. Gottfried, P. Bera and C. T. Campbell, J. Phys. Chem. B, 108, 14627-33, (2004). (Issue in honor of G. Ertl). reprint


Monocyte Activation on Polyelectrolyte Multilayers. J. J. Hwang, S. Jelacic, N. T. Samuel, R. V. Maier, C. T. Campbell, David G.Castner, Allan S. Hoffman, and P. S. Stayton, Journal of Biomaterials Science, Polymer Edition 16, 237-251, (2005).


A Streptavidin Linker Layer that Functions after Drying. N. Xia, J. Shumaker-Parry, H. Zareie, C. T. Campbell and D. G. Castner, Langmuir 20, 3710-16, (2004).


Microkinetic Modeling of Ethylene Oxidation over Silver. K. Stegelmann, N. C. Schiødt, C. T. Campbell and P. Stoltze, Journal of Catalysis 221, 630-649, (2004).


Microspotting Streptavidin and Double-Stranded DNA Arrays on Gold for High-Throughput Studies of Protein – DNA Interactions by SPR Microscopy. J. Shumaker-Parry, M. H. Zareie, R. A. Aebersold and C. T. Campbell, Anal. Chem. 76, 918-929, (2004). reprint


Quantitative Methods for Spatially-Resolved Adsorption / Desorption Measurements in Real Time by SPR Microscopy. J. Shumaker-Parry and C. T. Campbell, Anal. Chem. 76, 907-917, (2004). reprint


Waltzing with O2 (Perspective: Surface Science). C. T. Campbell, Science, 299, 357, (2003). reprint


Adsorption and Adhesion Energies of Pb on (1x1)-Mo2 C / Mo(100) by Calorimetry. M. Smedh, S. F. Diaz and C. T. Campbell, Phys. Rev. B 67, art. no. 205401, (2003).


Cyclohexane Dehydrogenation and H2 Adsorption on Pt Particles on ZnO(0001)-O. A. W. Grant, L. T. Ngo, K. Stegelman and C. T. Campbell, J. Phys. Chem. B 107, 1180-1188, (2003).


Benzene Adsorption and Dehydrogenation on Pt / ZnO(0001)-O Model Catalysts. L. T. Ngo, L. Xu, A. W. Grant and C. T. Campbell, J. Phys. Chem. B 107, 1174-1179, (2003).


Heat of Adsorption of Cu and Pb on Hydroxyl-covered MgO(100). D. E. Starr, S. F. Diaz, J. E. Musgrove, J. T. Ranney, D. J. Bald, L. Nelen, H. Ihm and C. T. Campbell, Surface Sci. 515, 13-20, (2002).


Education in Nanotechnology: Launching the First Ph.D. Program. V. Vogel and C. T. Campbell, International Journal of Engineering Education 18, 498-505, (2002).


Catalysts Under Pressure (Perspectives: Surface Science), Charles T. Campbell, Science 294, 1471-2, (2001).


Geometry of C1-3 oxygenates on ZnO(0001)-Zn. A. Gutiérrez-Sosa, T. M. Evans, S. C. Parker, C. T. Campbell, G. Thornton, Surface Sci. 497, 239-46, (2002).


Propene adsorption on gold particles on TiO2(110). H. M. Ajo, V. A. Bondzie and C. T. Campbell, Catalysis Letters 78, 359-68, (2002).


Finding the Rate-Determining Step in a Mechanism:  Comparing DeDonder Relations with the “Degree of Rate Control”. C. T. Campbell, J. Catal. 204, 520-4, (2001).


Methanol Decomposition on Pt/ZnO(0001)-Zn Model Catalysts. A. W. Grant, J. H. Larsen, C. A. Perez, S. Lehto, M. Schmal and C. T. Campbell, J. Phys. Chem. 105, 9273-9, (2001).


Measurement of the energetics of metal film growth on a semiconductor substrate:  Ag / Si(100)-2x1. D. E. Starr, J. T. Ranney, J. H. Larsen, J. E. Musgrove and C. T. Campbell, Phys. Rev. Letters 87, 106102, (2001).


Protein contact printing for a surface plasmon resonance biosensor with on-chip referencing. H.B. Lu, J. Homola, C. T. Campbell, G. G. Nenninger, S. S. Yee and B. D. Ratner, Sensors and Actuators B 74, 91-99, (2001).


Low-temperature adsorption microcalorimetry:  Pb/MgO(100). D. E. Starr and C. T. Campbell, (invited paper: John Yates Festschrift), J. Phys. Chem. B 105, 3776-82, (2001).


Future directions in catalysis science – Workshop, G. A. Somorjai, S. Benkovic, C. T. Campbell and 34 other authors, Catalysis Letters 76, 111-124, (2001).


Orientation of benzene and phenoxy on the polar ZnO(0001)-Zn surface. A. Gutierrez-Sosa, T. M. Evans, S. C. Parker, C. T. Campbell and G. Thornton, J. Phys. Chem. B 105, 3783-3785, (2001).


Microcalorimetric measurements of the heat of adsorption of Pb on well-defined oxides:  MgO(100) and p(2x1)-oxide on Mo(100). D. E. Starr, D. J. Bald, J. E. Musgrove, J. T. Ranney and C. T. Campbell, J. Chem. Phys. 114, 3752-64, (2001).


Adsorption energetics of Ag on  MgO(100). J. H. Larsen, J. T. Ranney, D. E. Starr, J. E. Musgrove and C. T. Campbell, Phys. Rev. B 63, 195410 (8 pages), (2001).


Model Oxide-Supported Metal Catalysts: Energetics, Particle Thicknesses, Chemisorption and Catalytic Properties. C. T. Campbell, A. W. Grant, D. E. Starr, S. C. Parker and V. E. Bondzie, Topics in Catalysis (invited paper in issue honoring Gabor Somorjai), 14, 43-51, (2001).


Enthalpies of Adsorption of Metal Atoms on Single-Crystalline Surfaces by Microcalorimetry. J. H. Larsen, D. E. Starr, C. T. Campbell, J. Chemical Thermodynamics 33, 333-345, (2001).


Modifying Behaviour of Cu on the Orientation of Formate on ZnO(000-1)-O. A. Gutierrez-Sosa, T. Evans, A. P. Woodhead, R. Lindsay, C. A. Muryn, G. Thornton, J. Yoshihara, S. C. Parker and C. T. Campbell, Surface Sci. 477, 1-7, (2001).


Surface Characterization of Mixed Self-Assembled Monolayers Designed for Streptavidin Immobilization. K. E. Nelson, L. S. Jung, L. Gamble, M. Boeckl., E. Naeemi, S. L. Golledge, T. Sasaki, D. G. Castner, C. T. Campbell and P. Stayton, Langmuir 17, 2807-16, (2001).


Sticking Probabilities in Adsorption of Alkylthiols from Liquid Ethanol Solution onto Gold. L. S. Jung and C. T. Campbell, J. Phys. Chem. 104, 11168-78, (2000).


Probing Protein: DNA Interactions Using a Uniform Monolayer of DNA and Surface Plasmon Resonance. by J. S. Shumaker-Parry, C. T. Campbell, G. D. Stormo, F. S. Silbaq, R. H. Aebersold, in Scanning and Force Microscopies for Biomedical Applications II, S. Nie, E. Tayima and E. S. Yeung, eds., Proceedings of SPIE, Vol. 3922, 158-166 (2000).


Binding and Dissociation Kinetics of Wild-Type and Mutant Streptavidins on Mixed Biotin-Containing Alkylthiolate Monolayers. by Linda S. Jung, Kjell E. Nelson, P. S. Stayton and Charles T. Campbell, Langmuir 16, 9421-32, (2000).


Sticking Probabilities in Adsorption from Liquid Solutions:  Alkylthiols on Gold. L. S. Jung and C. T. Campbell,  Phys. Rev. Letters 84, 5164-67, (2000).


The Influence of Chlorine on the Dispersion of Cu Particles on Cu/ZnO(0001) Model Catalysts. by Ann W. Grant, Jeffrey T. Ranney, Charles T. Campbell, T. Evans and G. Thornton, Catalysis Letters 65, 159-68, (2000).


Quantification of Tight Binding to Surface-Immobilized Phospholipid Vesicles using Surface Plasmon Resonance: Binding Constant of Phospholipase A2. L. S. Jung, J. S. Shumaker-Parry, C. T. Campbell, S. S. Yee and M. H. Gelb, J. Am. Chem. Soc. 122, 4177-84, (2000).


Surface Characterization of Hydroxyapatite and Related Calcium Phosphates by XPS and TOF-SIMS, H. B. Lu, C. T. Campbell and B. D. Ratner, Analytical Chemistry 72, 2886-94, (2000).


The Kinetics of CO Oxidation by Adsorbed Oxygen on Well-Defined Gold Particles on TiO2 (110). V. Bondzie, S. C. Parker and C. T. Campbell, Catalysis Letters 63, 143-151, (1999).


Back to Research Interests

Back to Research Interests

Awards & Activities

  • National President, Phi Lambda Upsilon, Honorary Chemical Society (2002-05)
  • St. John's College, Cambridge University, England, Overseas Visiting Scholar Fellowship (1996)
  • Chair, Colloid and Surface Chemistry Division of the American Chemical Society (1993)
  • John Yarwood Memorial Award of the British Vacuum Council (1989)
  • Camille and Henry Dreyfus Foundation Teacher/Scholar Award (1988‑92)
  • DuPont Young Faculty Award (1988‑89)
  • Alfred P. Sloan Research Fellowship (1986‑88)

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