Karen Goldberg

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2017

Oxidative Addition of Iodine to (tBu)4(POCOP)Ir(CO) Complexes
Goldberg, J. M.; Berman, J. L.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. J. Organomet. Chem. 2017, In Press

The Effect of the cis-donor in pincer ligands on hydrogenolysis of Pd-OH: A DFT study
Parkes, M. V.; Bailey, W. D.; Goldberg, K. I.; Kemp, R. A. J. Organomet. Chem. 2017, In Press

β-Hydride elimination and C-H activation by an iridium acetate complex, catalyzed by Lewis acids. Alkane dehydrogenation cocatalyzed by Lewis acids and [2,6-Bis(4,4-dimethyloxazolinyl)-3,5-dimethylphenyl]iridium
Gao, Y.; Guan, C.; Zhou, M.; Kumar, A.; Emge, T. J.; Wright, A. M.; Goldberg, K. I.; Krogh-Jespersen, K.; Goldman, A. S. J. Am. Chem. Soc. 2017, 139, 6338-6350.

Large-Scale Selective Functionalization of Alkanes
Goldberg, K. I.; Goldman, A. S. Acc. Chem. Res. 2017, 50, 620-626.

2016

Hydrogen Addition to (pincer)IrI(CO) Complexes: The Importance of Steric and Electronic Factors
Goldberg, J. M.; Cherry, S. D. T.; Guard, L. M.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. Organometallics 2016, 35, 3546-3556.

High Catalytic Efficiency Combined with High Selectivity for the Aldehyde-Water Shift Reaction using (para-cymene)Ruthenium Precatalysts
Brewster, T. P.; Goldberg, J. M.; Tran, J. C.; Heinekey, D. Michael; Goldberg, K. I. ACS Catal., 2016, 6, 6302-6305.

Base-Free Iridium-Catalyzed Hydrogenation of Esters and Lactones
Brewster, T. P.; Rezayee, N. M.; Culakova, Z.; Sanford, M. S.; Goldberg, K. I. ACS Catal. 2016, 6, 3113-3117.

2015

The Importance of Steric Factors in Iridium Pincer Complexes
Goldberg, J. M.; Wong, G. W.; Brastow, K. E.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. Organometallics 2015, 34, 753-762.

Pyrazole-Based PCN Pincer Complexes of Palladium(II): Mono- and Dinuclear Hydroxide Complexes and Ligand Rollover C–H Activation
Bailey, W. D.; Luconi, L.; Rossin, A.; Yakhvarov, D.; Flowers, S. E.; Kaminsky, W.; Kemp, R. A.; Giambastiani, G.; Goldberg, K. I. Organometallics 2015, 34, 3998-4010.

2014

Bailey, W. D. Parkes, M. V.; Kemp, R. A.; and Goldberg, K. I., Reactions of Square-Planar d8 Pincer Complexes with Oxygen and Hydrogen. In Pincer and Pincer-Type Complexes: Applications in Organic Synthesis and Catalysis, Szabo, K., J. and Wendt, Ola F., Ed. Wiley-VCH 2014; pp 281-298.

Organometallics Roundtable 2013–2014
Gladysz, J. A.; Bedford, R. B.; Fujita, M.; Gabbaı̈, F. P.; Goldberg, K. I.; Holland, P. L.; Kiplinger, J. L.; Krische, M. J.; Louie, J.; Lu, C. C.; Norton, J. R.; Petrukhina, M. A.; Ren, T.; Stahl, S. S.; Tilley, T. D.; Webster, C. E.; White, M. C.; Whiteker, G. T Organometallics 2014, 33, 1505-1527.

Platinum(II) Olefin Hydroarylation Catalysts: Tuning Selectivity for the anti-Markovnikov Product
Clement, M. L.; Grice, K. A.; Luedtke, A. T.; Kaminsky, W.; Goldberg, K. I. Chemistry- A European Journal 2014, 20, 17287.

Understanding the Effect of Ancillary Ligands on Concerted Metalation-Deprotonation by (dmPhebox)Ir(OAc)2(H2O) Complexes: A DFT Study
Pahls, D. R.; Allen, K. E.; Goldberg, K. I.; Cundari, T. R. Organometallics 2014, 33, 6413.

Reactions of Pd and Pt Complexes with Molecular Oxygen
Scheuermann, M. L.; Goldberg K. I. Chemistry- A European Journal 2014, 20, 14556.

Iridium, Rhodium, and Ruthenium Catalysts for the "Aldehyde-Water Shift" Reaction
Brewster, T. P.; Ou, W. C.; Tran, J. C.; Goldberg, K. I.; Hanson, S. K.; Cundari, T. R.; Heinekey, D. M. ACS Catalysis 2014, 4, 3034.

Hemilability of P(X)N-type ligands (X = O, N-H): rollover cyclometalation and benzene C-H activation from (P(X)N)PtMe2 complexes
Scheuermann, M. L.; Grice, K. A.; Ruppel, M. J.; Rossello-Merino, M.; Kaminsky W.; Goldberg, K. I. Dalton Trans. 2014, 43, 12018.

Methylplatinum(II) and Molecular Oxygen: Oxidation to Methylplatinum(IV) in Competition with Methyl Group Transfer to Form Dimethylplatinum(IV)
Prantner, J. D.; Kaminsky, W.; Goldberg, K. I. Organometallics 2014, 33, 3227.

Oxygen-Promoted C-H Bond Activation at Palladium
Scheuermann, M. L..; Boyce, D. W.; Grice, K. A.; Kaminsky, W.; Stoll, S.; Tolman, W. B.; Swang, O.; Goldberg, K. I. Angew. Chem. Int. Ed. 2014, 53, 6492.

Synthesis and Characterization of Anionic, Neutral, and Cationic PNP Pincer Pd(II) and Pt(II) Hydrides
Bailey, W. D.; Kaminsky W.; Kemp, R. A.; Goldberg, K. I. Organometallics 2014, 33, 2503.

Regeneration of an Iridium(III) Complex Active for Alkane Dehydrogenation Using Molecular Oxygen
Allen, K. E.; Heinekey, D. M.; Goldman, A. S.; Goldberg, K. I. Organometallics 2014, 33, 1337.

Arene Activation at Iridium Facilitates C-O Bond Cleavage of Aryl Ethers
Miller, A. J. M.; Kaminsky, W.; Goldberg, K. I. Organometallics 2014, 33, 1245.

2013

Hydrogenation of Carboxylic Acids Catalyzed by Half-Sandwich Complexes of Iridium and Rhodium
Brewster, T. P.; Miller, A. J. M.; Heinekey, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2013, 135, 16022.

Partial Deoxygenation of Glycerol Catalyzed by Iridium Pincer Complexes
Lao, D. B.; Owens, A. C. E.; Heinekey, D. M.; Goldberg, K. I. ACS Catalysis 2013, 3, 2391.

Reactions of Five-Coordinate Platinum(IV) Complexes with Molecular Oxygen
Scheuermann, M. L; Luedtke, A. T.; Hanson, S. K.; Fekl, U.; Kaminsky, W.; Goldberg, K. I. Organometallics 2013, 32, 4752.

Synthesis and Characterization of Iridium(I) and Iridium(III) Complexes Containing Dialkylbiphenylphosphines
O'Connor, A. R.; Kaminsky, W.; Chan, B. C.; Heinekey, D. M.; Goldberg, K. I. Organometallics 2013, 32, 4016.

Catalytic Disproportionation of Formic Acid to Generate Methanol
Miller, A. J. M.; Heinekey, D. M.; Mayer, J. M.; Goldberg, K. I. Angew. Chem. Int. Ed. 2013, 52, 3981.

Alkane Dehydrogenation by C-H Activation at Iridium(III)
Allen, K. E.; Heinekey, D. M.; Goldman, A. S.; Goldberg, K. I. Organometallics 2013, 32, 1570.

Generation and Structural Characterization of a Gold(III) Alkene Complex
Langseth, E.; Scheuermann, M. L.; Balcells, D.; Kaminsky, W.; Goldberg, K. I.; Eisenstein, O.; Heyn, R. H.; Tilset, M. Angew. Chem. Int. Ed. 2013, 52, 1660.

Pincer Complexes as Catalysts for Amine Borane Dehydrogenation
St. John, A.; Goldberg, K. I.; Heinekey, D. M. Top. Organomet. Chem. 2013, 40, 271.

2012

Reactions of Late Transition Metal Complexes with Molecular Oxygen
Boisvert. L; Goldberg, K. I. Accounts of Chemical Research 2012, 45, 899.

A Soluble Copper-bipyridine Water-oxidation Electrocatalyst
Barnett, S. M.; Goldberg, K. I.; Mayer, J. M. Nature Chem. 2012, 4, 498.

Partial Deoxygenation of 1,2-Propanediol Catalyzed by Iridium Pincer Complexes
Ahmed Foskey, T. J.; Heinekey, D. M.; Goldberg, K. I. ACS Catalysis 2012, 2, 1285.

η6 Tetramethylfulvene and μ-η3:η3-Benzene Complexes of Iridium
Meredith, J. M.; Goldberg, K. I.; Kaminsky, W. Heinekey, D. M. Organometallics 2012, 31, 8459-8462.

Catalytic Arene H/D Exchange with Novel Rhodium and Iridium Complexes
Rhinehart, J. L.; Manbeck, K. A.; Buzak, S. K.; Lippa G. M.; Brennessel, W. W.; Goldberg, K. I.; Jones, W. D. Organometallics 2012, 31, 1943.

C-H Bond Activation by Cationic Iridium(III) NHC Complexes: A Combined Experimental and Computational Study
Meredith, J. M.; Robinson, R.; Goldberg, K. I.; Kaminsky, W.; Heinekey, D. M. Organometallics 2012, 31, 1879.

2011

Hydrogenolysis of Palladium(II) Hydroxide, Phenoxide, and Alkoxide Complexes
Fulmer, G. R.; Herndon, A. N.; Kaminsky, W.; Kemp, R. A.; Goldberg, K. I. J. Am. Chem. Soc. 2011, 133, 17713.

Syntheses and Characterization of Palladium Complexes with a Hemilabile “PCO” Pincer Ligand
Fulmer, G. R.; Kaminsky, W.; Kemp, R. A.; Goldberg, K. I. Organometallics 2011, 30, 1627.

Five-Coordinate Platinum(IV) Complexes
Grice, K. A.; Scheuermann, M. L.; Goldberg, K. I. Top. Organomet. Chem. 2011, 503, 1.

Preparation of a Dihydrogen Complex of Cobalt
Hebden, T. J.; St. John, A. J.; Gusev, D. G.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. Angew. Chem. Int. Ed. 2011, 50, 1873.

C–H Activation of Benzene by Platinum(II) Complexes with Cyclometalated Phosphine Ligands
Grice, K. A.; Kaminsky, W.; Goldberg, K. I. Inorg. Chim. Acta 2011, 369, 76.

2010

Metal-Ligand Cooperativity in O2 Activation: Observation of a “Pt-O-O-C” Peroxo Intermediate
Scheuermann, M. L.; Fekl, U.; Kaminsky, W.; Goldberg, K. I. Organometallics 2010, 29, 4749.

NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in DeuteratedSolvents Relevant to the Organometallic Chemist
Fulmer, G. R.; Miller, A. J. M.; Sherden, N. H.; Gottlieb, H. E.; Nudelman, A.; Stoltz, B. M.; Bercaw, J. E.; Goldberg, K. I. Organometallics 2010, 29, 2176.

2009

Characterization of a Rhodium(I) σ-Methane Complex in Solution
Bernskoetter, W. H.; Schauer, C. K.; Goldberg, K. I.; Brookhart, M. Science 2009, 553.

Insertion of Molecular Oxygen into a Palladium(II) Methyl Bond: A Radical Chain Mechanism Involving Palladium(III) Intermediates
Boisvert, L.; Denney, M. C.; Hanson, S. K.; Goldberg, K. I. J. Am. Chem. Soc. 2009, 131, 15802.

Investigations of Iridium-Mediated Reversible C-H Bond Cleavage: Characterization of a 16-Electron Iridium(III) Methyl Hydride Complex
Bernskoetter, W. H.; Kloek-Hanson, S. ; Buzak, S. K.; Davis, Z.; White, P. S.; Swartz, R.; Goldberg, K. I.; Brookhart, M. J. Am. Chem. Soc. 2009, 131, 8603.

Synthesis, Characterization, and Reactivity of Nickel Hydride Complexes Containing 2,6-C6H3(CH2PR2)2 (R = tBu, cHex, and iPr) Pincer Ligands
Boro, B. J.; Duesler, E. N.; Goldberg, K. I.; Kemp, R. A. Inorg. Chem. 2009, 48, 5081.

Dinuclear Iridium Complexes Containing Cp* and Carbonyl Ligands: Synthesis, Structure, and Reactivity
Meredith, J. M.; Goldberg, K. I.; Kaminsky, W. ;Heinekey, D. M. Organometallics 2009, 28, 3546.

Insertion of Dioxygen into a Platinum(II)−Methyl Bond To Form a Platinum(II) Methylperoxo Complex
Grice, K. A.; Goldberg, K. I. Organometallics 2009, 28, 953.

Autoxidation of Platinum(IV) Hydrocarbyl Hydride Complexes To Form Platinum(IV) Hydrocarbyl Hydroperoxide Complexes
Look, J. L.; Wick, D. D.; Mayer, J. M.; Goldberg, K. I. Inorg. Chem. 2009, 48, 1356.

Hydrogenolysis of Palladium(II) Hydroxide and Methoxide Pincer Complexes
Fulmer, G. R.; Muller, R. P.; Kemp, R. A.; Goldberg, K. I. J. Am. Chem. Soc. 2009, 131, 1346.

Reductive Elimination and Dissociative β-Hydride Abstraction from Pt(IV) Hydroxide and Methoxide Complexes
Smythe, N. A.; Grice, K. A.; Williams, B. S.; Goldberg, K. I. Organometallics 2009, 28, 277.

2008

An Unprecedented Bonding Mode for Potassium within a PCP-Pincer Palladium Hydride-K-Selectride® Complex
Boro, B. J.; Duesler, E. N.; Goldberg, K. I.; Kemp, R. A. Inorg. Chem. Commun. 2008, 11, 1426.

Iridium-Catalyzed Dehydrogenation of Substituted Amine Boranes: Kinetics, Thermodynamics, and Implications for Hydrogen Storage
Dietrich, B. L.; Goldberg, K. I.; Heinekey, D. M.; Autrey, T.; Linehan, J. C. Inorg. Chem. 2008, 47, 8583.

Intermolecular Hydroarylation of Unactivated Olefins Catalyzed by Homogeneous Platinum Complexes
Luedtke A. T.; Goldberg, K. I. Angew. Chem. Int. Ed. 2008, 47, 7694.

σ-Borane Complexes of Iridium: Synthesis and Structural Characterization
Hebden, T. J.; Denney, M. C.; Pons, V.; Piccoli, P. M. B.; Koetzle, T. F.; Schultz, A. J.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. J. Am. Chem. Soc. 2008, 130, 10812.

C-H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H-D Exchange between Arenes and Water
Kloek-Hanson, S. M.; Heinekey, D. M.; Goldberg, K. I. Organometallics 2008, 27, 1454.

Reactions of Iridium Hydride Pincer Complexes with Dioxygen: New Peroxo Complexes and Reversible O2 Binding
Williams, D. B.; Kaminsky, W.; Mayer, J. M.; Goldberg, K. I. Chem. Commun. 2008, 35, 4195.

2007

Reductive Elimination of Ethane from Five-Coordinate Platinum(IV) Alkyl Complexes
Luedtke, A. T.; Goldberg, K. I. Inorg. Chem. 2007, 46, 8496.

Alkyl Carbon-Nitrogen Reductive Elimination from Platinum(IV)-Sulfonamide Complexes
Pawlikowski, A. V.; Getty, A. D.; Goldberg, K. I. J. Am. Chem. Soc. 2007, 129, 10382.

C-H bond Activation by Rhodium(I) Hydroxide and Phenoxide Complexes
Kloek, S. M.; Heinekey, D. M.; Goldberg, K. I. Angew. Chem. Int. Ed. 2007, 46, 4736.

Competitive C-H Bond Activation and β-Hydride Elimination at Platinum(II)
Kloek, S. M.; Goldberg, K. I. J. Am. Chem. Soc. 2007, 129, 3460.

2006

Mechanism of Direct Molecular Oxygen Insertion in a Palladium(II)-Hydride Bond
Keith, J. M.; Muller, R. P.; Kemp, R. A.; Goldberg, K. I.; Goddard, W. A.; Oxgaard, J. Inorg. Chem. 2006, 45, 9631.

Efficient Catalysis of Ammonia Borane Dehydrogenation
Denney, M. C.; Pons, V.; Hebden, T. J.; Heinekey, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2006, 128, 12048.

Stereoselective Decarbonylation of Methanol to Form a Stable Iridium(III) trans-Dihydride Complex
Kloek, S. M.; Heinekey, D. M.; Goldberg, K. I. Organometallics 2006, 25, 3007.

Insertion of Molecular Oxygen into a Palladium(II) Hydride Bond
Denney, M. C.; Smythe, N. A.; Cetto, K. L.; Kemp, R. A.; Goldberg, K. I. J. Am. Chem. Soc. 2006, 128, 2508.

2005

Mechanistic Information on the Reductive Elimination from Cationic Trimethylplatinum(IV) Complexes to Form Carbon-Carbon Bonds
Procelewska, J.; Zahl, A.; Liehr, G.; van Eldik, R.; Smythe, N. A.; Williams, B. S.; Goldberg, K. I. Inorg. Chem. 2005, 44, 7732.

The gem-Dialkyl Effect as a Test for Preliminary Diphosphine Chelate Opening in a Reductive Elimination Reaction
Arthur, K. L.; Wang, Q. L.; Bregel, D. M.; Smythe, N. A.; O'Neill, B. A.; Goldberg, K. I.; Moloy K. G. Organometallics 2005, 24, 4624.

2003

β-Diiminate Platinum Complexes for Alkane Dehydrogenation
Fekl, U.; Kaminsky, W.; Goldberg, K. I. J. Am. Chem. Soc. 2003, 125, 15286.

Reductive Elimination/Oxidative Addition of Carbon-Hydrogen Bonds at Pt(IV)/Pt(II) Centers: Mechanistic Studies of the Solution Thermolyses of TpMe2Pt(CH3)2H
Jenson, M. P.; Wick, D. D.; Reinartz, S.; White, P. S.; Templeton, J, L.; Goldberg, K. I. J. Am. Chem. Soc. 2003, 125, 8610.

Homogeneous Hydrocarbon C-H Bond Activation and Functionalixation with Platinum
Fekl, U.; Goldberg, K. I. Adv. Inorg. Chem. 2003, 54, 259.

Mechanisms of C-C and C-H Alkane Reductive Eliminations from Octahedral Pt(IV): Reaction via Five-Coordinate Intermediates or Direct Elimination?
Crumpton-Bregel, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2003, 125, 9442.

2002

Five-Coordinate Platinum(IV) Complex as a Precursor to a Novel Pt(II) Olefin Hydride Complex for Alkane Activation
Fekl, U.; Goldberg, K. I. J. Am. Chem. Soc. 2002, 124, 6804.

2001

Stable Five-Coordinate Platinum(IV) Alkyl Complex
Fekl, U.; Kaminsky, W.; Goldberg, K. I. J. Am. Chem. Soc. 2001, 123, 6423.

Reaction of a Palladium(II) Complex Chelated by a Tridentate PNC Ligand with Water to Produce a [(PN)Pd(-OH)]22+ Dimer: A Rare Observation of a Well-Defined Hydrolysis of a Pd(II)-Aryl Compound
Getty, A. D.; Goldberg, K. I. Organometallics 2001, 20, 2545.

Computational Study of Reductive Elimination Reactions to Form C-H Bonds from Platinum(II) and Platinum(IV) Centers with Strongly Coordinating Trimethylphosphine Ligands
Bartlett, K.L.; Goldberg, K. I.; Borden, W. T. Organometallics 2001, 20, 2669.

Studies of Reductive Elimination Reactions To Form Carbon-Oxygen Bonds from Pt(IV) Complexes
Williams, B. S.; Goldberg, K. I. J. Am. Chem. Soc. 2001, 123, 2576.

2000

Five-Coordinate Intermediates in Carbon-Carbon Reductive Elimination Reactions from Pt(IV)
Crumpton, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2000, 122, 962.

A Computational Study of Reductive Elimination Reactions to Form C-H Bonds from Pt(II) and Pt(IV) Centers. Why Does Ligand Loss Precede Elimination from Six-Coodinate but Not Four-Coodinate Platinum?
Bartlett, K. L.; Goldberg, K. I.; Borden, W. T. J. Am. Chem. Soc. 2000, 122, 1456.

1999

Direct Observation of C-O Reductive Elimination from Pt(IV)
Williams, B. S.; Holland, A. W.; Goldberg, K. I. J. Am. Chem. Soc. 1999, 121, 252.

Insertion of Dioxygen into a Platinum-Hydride Bond to Form a Novel Dialkylhydroperoxo Pt(IV) Complex
Wick, D. D.; Goldberg, K. I. J. Am. Chem. Soc. 1999, 121, 11900.

1997

C-H Activation at Pt(II) To Form Stable Pt(IV) Alkyl Hydrides
Wick, D. D.; Goldberg, K. I. J. Am . Chem. Soc. 1997, 119, 10235.