Karen Goldberg

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Hemilability of P(X)N-type ligands (X = O, N-H): rollover cyclometalation and benzene C-H activation from (P(X)N)PtMe2 complexes
Scheuermann, M. L.; Grice, K. A.; Ruppel, M. J.; Rossello-Merino, M.; Kaminsky W.; Goldberg, K. I. Dalton Trans. 2014 Advance Article.

Methylplatinum(II) and Molecular Oxygen: Oxidation to Methylplatinum(IV) in Competition with Methyl Group Transfer to Form Dimethylplatinum(IV)
Prantner, J. D.; Kaminsky, W.; Goldberg, K. I. Organometallics 2014, Article ASAP.

Oxygen-Promoted C-H Bond Activation at Palladium
Scheuermann, M. L..; Boyce, D. W.; Grice, K. A.; Kaminsky, W.; Stoll, S.; Tolman, W. B.; Swang, O.; Goldberg, K. I. Angew. Chem. Int. Ed. 2014, 53, 6492.

Synthesis and Characterization of Anionic, Neutral, and Cationic PNP Pincer PdII and PtII Hydrides
Bailey, W. D.; Kaminsky W.; Kemp, R. A.; Goldberg, K. I. Organometallics 2014, 33, 2503.

Regeneration of an Iridium(III) Complex Active for Alkane Dehydrogenation Using Molecular Oxygen
Allen, K. E.; Heinekey, D. M.; Goldman, A. S.; Goldberg, K. I. Organometallics 2014, 33, 1337.

Arene Activation at Iridium Facilitates C-O Bond Cleavage of Aryl Ethers
Miller, A. J. M.; Kaminsky, W.; Goldberg, K. I. Organometallics 2014, 33, 1245.

Hydrogenation of Carboxylic Acids Catalyzed by Half-Sandwich Complexes of Iridium and Rhodium
Brewster, T. P.; Miller, A. J. M.; Heinekey, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2013, 135, 16022.

Partial Deoxygenation of Glycerol Catalyzed by Iridium Pincer Complexes
Lao, D. B.; Owens, A. C. E.; Heinekey, D. M.; Goldberg, K. I. ACS Catalysis 2013, 3, 2391.

Reactions of Five-Coordinate Platinum(IV) Complexes with Molecular Oxygen
Scheuermann, M. L; Luedtke, A. T.; Hanson, S. K.; Fekl, U.; Kaminsky, W.; Goldberg, K. I. Organometallics 2013, 32, 4752.

Synthesis and Characterization of Iridium(I) and Iridium(III) Complexes Containing Dialkylbiphenylphosphines
O'Connor, A. R.; Kaminsky, W.; Chan, B. C.; Heinekey, D. M.; Goldberg, K. I. Organometallics 2013, 32, 4016.

Catalytic Disproportionation of Formic Acid to Generate Methanol
Miller, A. J. M.; Heinekey, D. M.; Mayer, J. M.; Goldberg, K. I. Angew. Chem. Int. Ed. 2013, 52, 3981.

Alkane Dehydrogenation by C-H Activation at Iridium(III)
Allen, K. E.; Heinekey, D. M.; Goldman, A. S.; Goldberg, K. I. Organometallics 2013, 32, 1570.

Generation and Structural Characterization of a Gold(III) Alkene Complex
Langseth, E.; Scheuermann, M. L.; Balcells, D.; Kaminsky, W.; Goldberg, K. I.; Eisenstein, O.; Heyn, R. H.; Tilset, M. Angew. Chem. Int. Ed. 2013, 52, 1660.

Pincer Complexes as Catalysts for Amine Borane Dehydrogenation
St. John, A.; Goldberg, K. I.; Heinekey, D. M. Top. Organomet. Chem. 2013, 40, 271.

Reactions of Late Transition Metal Complexes with Molecular Oxygen
Boisvert. L; Goldberg, K. I. Accounts of Chemical Research 2012, 45, 899.

A Soluble Copper-bipyridine Water-oxidation Electrocatalyst
Barnett, S. M.; Goldberg, K. I.; Mayer, J. M. Nature Chem. 2012, 4, 498.

Partial Deoxygenation of 1,2-Propanediol Catalyzed by Iridium Pincer Complexes
Ahmed Foskey, T. J.; Heinekey, D. M.; Goldberg, K. I. ACS Catalysis 2012, 2, 1285.

Catalytic Arene H/D Exchange with Novel Rhodium and Iridium Complexes
Rhinehart, J. L.; Manbeck, K. A.; Buzak, S. K.; Lippa G. M.; Brennessel, W. W.; Goldberg, K. I.; Jones, W. D. Organometallics 2012, 31, 1943.

C-H Bond Activation by Cationic Iridium(III) NHC Complexes: A Combined Experimental and Computational Study
Meredith, J. M.; Robinson, R.; Goldberg, K. I.; Kaminsky, W.; Heinekey, D. M. Organometallics 2012, 31, 1879.

Hydrogenolysis of Palladium(II) Hydroxide, Phenoxide, and Alkoxide Complexes
Fulmer, G. R.; Herndon, A. N.; Kaminsky, W.; Kemp, R. A.; Goldberg, K. I. J. Am. Chem. Soc. 2011, 133, 17713.

Syntheses and Characterization of Palladium Complexes with a Hemilabile “PCO” Pincer Ligand
Fulmer, G. R.; Kaminsky, W.; Kemp, R. A.; Goldberg, K. I. Organometallics 2011, 30, 1627.

Five-Coordinate Platinum(IV) Complexes
Grice, K. A.; Scheuermann, M. L.; Goldberg, K. I. Top. Organomet. Chem. 2011, 503, 1.

Preparation of a Dihydrogen Complex of Cobalt
Hebden, T. J.; St. John, A. J.; Gusev, D. G.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. Angew. Chem. Int. Ed. 2011, 50, 1873.

C–H Activation of Benzene by Platinum(II) Complexes with Cyclometalated Phosphine Ligands
Grice, K. A.; Kaminsky, W.; Goldberg, K. I. Inorg. Chim. Acta 2011, 369, 76.

Metal-Ligand Cooperativity in O2 Activation: Observation of a “Pt-O-O-C” Peroxo Intermediate
Scheuermann, M. L.; Fekl, U.; Kaminsky, W.; Goldberg, K. I. Organometallics 2010, 29, 4749.

NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in DeuteratedSolvents Relevant to the Organometallic Chemist
Fulmer, G. R.; Miller, A. J. M.; Sherden, N. H.; Gottlieb, H. E.; Nudelman, A.; Stoltz, B. M.; Bercaw, J. E.; Goldberg, K. I. Organometallics 2010, 29, 2176.

Characterization of a Rhodium(I) σ-Methane Complex in Solution
Bernskoetter, W. H.; Schauer, C. K.; Goldberg, K. I.; Brookhart, M. Science 2009, 553.

Insertion of Molecular Oxygen into a Palladium(II) Methyl Bond: A Radical Chain Mechanism Involving Palladium(III) Intermediates
Boisvert, L.; Denney, M. C.; Hanson, S. K.; Goldberg, K. I. J. Am. Chem. Soc. 2009, 131, 15802.

Investigations of Iridium-Mediated Reversible C-H Bond Cleavage: Characterization of a 16-Electron Iridium(III) Methyl Hydride Complex
Bernskoetter, W. H.; Kloek-Hanson, S. ; Buzak, S. K.; Davis, Z.; White, P. S.; Swartz, R.; Goldberg, K. I.; Brookhart, M. J. Am. Chem. Soc. 2009, 131, 8603.

Synthesis, Characterization, and Reactivity of Nickel Hydride Complexes Containing 2,6-C6H3(CH2PR2)2 (R = tBu, cHex, and iPr) Pincer Ligands
Boro, B. J.; Duesler, E. N.; Goldberg, K. I.; Kemp, R. A. Inorg. Chem. 2009, 48, 5081.

Dinuclear Iridium Complexes Containing Cp* and Carbonyl Ligands: Synthesis, Structure, and Reactivity
Meredith, J. M.; Goldberg, K. I.; Kaminsky, W. ;Heinekey, D. M. Organometallics 2009, 28, 3546.

Insertion of Dioxygen into a Platinum(II)−Methyl Bond To Form a Platinum(II) Methylperoxo Complex
Grice, K. A.; Goldberg, K. I. Organometallics 2009, 28, 953.

Autoxidation of Platinum(IV) Hydrocarbyl Hydride Complexes To Form Platinum(IV) Hydrocarbyl Hydroperoxide Complexes
Look, J. L.; Wick, D. D.; Mayer, J. M.; Goldberg, K. I. Inorg. Chem. 2009, 48, 1356.

Hydrogenolysis of Palladium(II) Hydroxide and Methoxide Pincer Complexes
Fulmer, G. R.; Muller, R. P.; Kemp, R. A.; Goldberg, K. I. J. Am. Chem. Soc. 2009, 131, 1346.

Reductive Elimination and Dissociative β-Hydride Abstraction from Pt(IV) Hydroxide and Methoxide Complexes
Smythe, N. A.; Grice, K. A.; Williams, B. S.; Goldberg, K. I. Organometallics 2009, 28, 277.

An Unprecedented Bonding Mode for Potassium within a PCP-Pincer Palladium Hydride-K-Selectride® Complex
Boro, B. J.; Duesler, E. N.; Goldberg, K. I.; Kemp, R. A. Inorg. Chem. Commun. 2008, 11, 1426.

Iridium-Catalyzed Dehydrogenation of Substituted Amine Boranes: Kinetics, Thermodynamics, and Implications for Hydrogen Storage
Dietrich, B. L.; Goldberg, K. I.; Heinekey, D. M.; Autrey, T.; Linehan, J. C. Inorg. Chem. 2008, 47, 8583.

Intermolecular Hydroarylation of Unactivated Olefins Catalyzed by Homogeneous Platinum Complexes
Luedtke A. T.; Goldberg, K. I. Angew. Chem. Int. Ed. 2008, 47, 7694.

σ-Borane Complexes of Iridium: Synthesis and Structural Characterization
Hebden, T. J.; Denney, M. C.; Pons, V.; Piccoli, P. M. B.; Koetzle, T. F.; Schultz, A. J.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. J. Am. Chem. Soc. 2008, 130, 10812.

C-H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H-D Exchange between Arenes and Water
Kloek-Hanson, S. M.; Heinekey, D. M.; Goldberg, K. I. Organometallics 2008, 27, 1454.

Reactions of Iridium Hydride Pincer Complexes with Dioxygen: New Peroxo Complexes and Reversible O2 Binding
Williams, D. B.; Kaminsky, W.; Mayer, J. M.; Goldberg, K. I. Chem. Commun. 2008, 35, 4195.

Reductive Elimination of Ethane from Five-Coordinate Platinum(IV) Alkyl Complexes
Luedtke, A. T.; Goldberg, K. I. Inorg. Chem. 2007, 46, 8496.

Alkyl Carbon-Nitrogen Reductive Elimination from Platinum(IV)-Sulfonamide Complexes
Pawlikowski, A. V.; Getty, A. D.; Goldberg, K. I. J. Am. Chem. Soc. 2007, 129, 10382.

C-H bond Activation by Rhodium(I) Hydroxide and Phenoxide Complexes
Kloek, S. M.; Heinekey, D. M.; Goldberg, K. I. Angew. Chem. Int. Ed. 2007, 46, 4736.

Competitive C-H Bond Activation and β-Hydride Elimination at Platinum(II)
Kloek, S. M.; Goldberg, K. I. J. Am. Chem. Soc. 2007, 129, 3460.

Mechanism of Direct Molecular Oxygen Insertion in a Palladium(II)-Hydride Bond
Keith, J. M.; Muller, R. P.; Kemp, R. A.; Goldberg, K. I.; Goddard, W. A.; Oxgaard, J. Inorg. Chem. 2006, 45, 9631.

Efficient Catalysis of Ammonia Borane Dehydrogenation
Denney, M. C.; Pons, V.; Hebden, T. J.; Heinekey, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2006, 128, 12048.

Stereoselective Decarbonylation of Methanol to Form a Stable Iridium(III) trans-Dihydride Complex
Kloek, S. M.; Heinekey, D. M.; Goldberg, K. I. Organometallics 2006, 25, 3007.

Insertion of Molecular Oxygen into a Palladium(II) Hydride Bond
Denney, M. C.; Smythe, N. A.; Cetto, K. L.; Kemp, R. A.; Goldberg, K. I. J. Am. Chem. Soc. 2006, 128, 2508.

Mechanistic Information on the Reductive Elimination from Cationic Trimethylplatinum(IV) Complexes to Form Carbon-Carbon Bonds
Procelewska, J.; Zahl, A.; Liehr, G.; van Eldik, R.; Smythe, N. A.; Williams, B. S.; Goldberg, K. I. Inorg. Chem. 2005, 44, 7732.

The gem-Dialkyl Effect as a Test for Preliminary Diphosphine Chelate Opening in a Reductive Elimination Reaction
Arthur, K. L.; Wang, Q. L.; Bregel, D. M.; Smythe, N. A.; O'Neill, B. A.; Goldberg, K. I.; Moloy K. G. Organometallics 2005, 24, 4624.

β-Diiminate Platinum Complexes for Alkane Dehydrogenation
Fekl, U.; Kaminsky, W.; Goldberg, K. I. J. Am. Chem. Soc. 2003, 125, 15286.

Reductive Elimination/Oxidative Addition of Carbon-Hydrogen Bonds at Pt(IV)/Pt(II) Centers: Mechanistic Studies of the Solution Thermolyses of TpMe2Pt(CH3)2H
Jenson, M. P.; Wick, D. D.; Reinartz, S.; White, P. S.; Templeton, J, L.; Goldberg, K. I. J. Am. Chem. Soc. 2003, 125, 8610.

Homogeneous Hydrocarbon C-H Bond Activation and Functionalixation with Platinum
Fekl, U.; Goldberg, K. I. Adv. Inorg. Chem. 2003, 54, 259.

Mechanisms of C-C and C-H Alkane Reductive Eliminations from Octahedral Pt(IV): Reaction via Five-Coordinate Intermediates or Direct Elimination?
Crumpton-Bregel, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2003, 125, 9442.

Five-Coordinate Platinum(IV) Complex as a Precursor to a Novel Pt(II) Olefin Hydride Complex for Alkane Activation
Fekl, U.; Goldberg, K. I. J. Am. Chem. Soc. 2002, 124, 6804.

Stable Five-Coordinate Platinum(IV) Alkyl Complex
Fekl, U.; Kaminsky, W.; Goldberg, K. I. J. Am. Chem. Soc. 2001, 123, 6423.

Reaction of a Palladium(II) Complex Chelated by a Tridentate PNC Ligand with Water to Produce a [(PN)Pd(-OH)]22+ Dimer: A Rare Observation of a Well-Defined Hydrolysis of a Pd(II)-Aryl Compound
Getty, A. D.; Goldberg, K. I. Organometallics 2001, 20, 2545.

Computational Study of Reductive Elimination Reactions to Form C-H Bonds from Platinum(II) and Platinum(IV) Centers with Strongly Coordinating Trimethylphosphine Ligands
Bartlett, K.L.; Goldberg, K. I.; Borden, W. T. Organometallics 2001, 20, 2669.

Studies of Reductive Elimination Reactions To Form Carbon-Oxygen Bonds from Pt(IV) Complexes
Williams, B. S.; Goldberg, K. I. J. Am. Chem. Soc. 2001, 123, 2576.

Five-Coordinate Intermediates in Carbon-Carbon Reductive Elimination Reactions from Pt(IV)
Crumpton, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2000, 122, 962.

A Computational Study of Reductive Elimination Reactions to Form C-H Bonds from Pt(II) and Pt(IV) Centers. Why Does Ligand Loss Precede Elimination from Six-Coodinate but Not Four-Coodinate Platinum?
Bartlett, K. L.; Goldberg, K. I.; Borden, W. T. J. Am. Chem. Soc. 2000, 122, 1456.

Direct Observation of C-O Reductive Elimination from Pt(IV)
Williams, B. S.; Holland, A. W.; Goldberg, K. I. J. Am. Chem. Soc. 1999, 121, 252.

Insertion of Dioxygen into a Platinum-Hydride Bond to Form a Novel Dialkylhydroperoxo Pt(IV) Complex
Wick, D. D.; Goldberg, K. I. J. Am. Chem. Soc. 1999, 121, 11900.

C-H Activation at Pt(II) To Form Stable Pt(IV) Alkyl Hydrides
Wick, D. D.; Goldberg, K. I. J. Am . Chem. Soc. 1997, 119, 10235.