Publications
28. Maloney, T. P.; Dohoda, A. F.; Zhu, A. C., Michael, F. E.
"Stereoretentive and Regioselective Selenium-catalyzed Intermolecular Propargylic C-H Amination of Alkynes”
Chem. Sci.
2022,
13,
Accepted Manuscript
DOI: 10.1039/D1SC07067C
27. Teh, W. P.; Obenschain, D. C.; Black, B. M., Michael, F. E.
"Catalytic Metal-free Allylic C-H Amination of Terpenoids”
J. Am. Chem. Soc.
2020,
142,
16717-16722.
DOI: 10.1021/jacs.0c06997
26. Tabor, J. R.; Obenschain, D. C.; Michael, F. E.
"Selenophosphoramide-Catalyzed Diamination and Oxyamination of Alkenes”
Chem. Sci.
2020,
11,
1677-1682.
DOI: 10.1039/C9SC05335B
25. Zheng, T.; Tabor, J. R.; Stein, Z. L.; Michael, F. E.
“Regioselective Metal-Free Aza-Heck Reactions of Terminal Alkenes Catalyzed by Phosphine Selenides”
Org. Lett.
2018,
20,
6975-6978.
DOI: 10.1021/acs.orglett.8b03159
24. Teh, W. P.; Michael, F. E.
“Palladium-Catalyzed Cross-Coupling of N-Sulfonylaziridines and Alkenylboronic Acids: Stereospecific Synthesis of Homoallylic Amines with Di-and Trisubstituted Alkenes”
Org. Lett.
2017,
19,
1738-1740.
DOI: 10.1021/acs.orglett.7b00504
23. Ingalls, E. L.; Holtzen, G. A.; Kaminsky, W.; Michael, F. E.
“Synthesis and Structural Characterization of Palladium(II) Complexes of Chiral Bidentate N-Heterocyclic Carbene-Quinoline Ligands”
J. Organomet. Chem.
2017,
832,
9-11.
DOI: 10.1016/j.jorganchem.2017.01.008
22. Rosewall, C. F.; Ingalls, E. L.; Kaminsky, W.; Michael, F. E.
“Chelation-driven Rearrangement of Primary Alkyl Aminopalladation Products to Stable Trisubstituted Alkyl Palladium Complexes”
Angew. Chem. Int. Ed.
2015,
54,
4557-4560.
DOI: 10.1002/anie.201412033
21. Duda, M. L.; Michael, F. E.
“Palladium-Catalyzed Cross-Coupling of N-Sulfonylaziridines with Boronic Acids”
J. Am. Chem. Soc.
2013,
135,
18347-18349.
DOI: 10.1021/ja410686v
20. Pierson, J.; Ingalls, E. L.; Vo, R.; Michael, F. E.
“Palladium(II)-Catalyzed Intramolecular Hydroamination of 1,3-Dienes to Give Homoallylic Amines”
Angew. Chem. Int. Ed.
2013,
52,
13311-13313.
DOI: 10.1002/anie.201305766
19. McGhee, A.; Cochran, B. M.; Stenmark, T.; Michael F. E.
“Stereoselective synthesis of 2,5-disubstituted morpholines using a palladium-catalyzed hydroamination reaction”
Chem. Comm.
2013,
49,
6800-6802.
DOI: 10.1039/C3CC44117B
18. Ingalls, E. L.; Sibbald, P. A.; Kaminsky, W.; Michael, F. E.
“Enantioselective Palladium-Catalyzed Diamination of Alkenes Using N-Fluorobenzenesulfonamide”
J. Am. Chem. Soc.
2013,
135,
8854-8856.
DOI: 10.1021/ja4043406
17. Okamoto, K.; Housekeeper, J. B.; Michael, F. E.; Luscombe, C. K.
“Thiophene based hyperbranched polymers with tunable branching using direct arylation methods”
Polym. Chem.
2013,
4,
3499-3506.
DOI: 10.1039/C3PY00412K
16. Bjelic, S.; Nivon, L. G.; Celebi-Olcum, N.; Kiss, G.; Rosewall, C. F.; Lovick, H. M.; Ingalls, E. L.; Gallaher, J. L.; Seetharaman, J.; Lew, S.; Montelione, G. T.; Hunt, J. F.; Michael, F. E.; Houk, K. N.; Baker, D.
“Computational Design of Enone-Binding Proteins with Catalytic Activity for the Morita-Baylis-Hillman Reaction”
ACS Chemical Biology
2013,
8,
749-757.
DOI: 10.1021/cb3006227
15. Liskin, D. V.; Sibbald, P. A.; Rosewall, C. F.; Michael, F. E.
“Palladium Catalyzed Alkoxyamination of Alkenes with Use of N-Fluorobenzenesulfonimide as Oxidant.”
J. Org. Chem.
2010,
75,
6294–6296.
DOI: 10.1021/jo101171g
14. Siegel, J. B.; Zanghellini, A.; Lovick, H. M.; Kiss, G.; Lambert, A. R.; St.Clair, J. L.; Gallaher, J. L.; Hilvert, D.; Gelb, M. H.; Stoddard, B.; Houk, K. N.; Michael, F. E.; Baker, D.
“Computational design of an enzyme catalyst for a stereoselective bimolecular Diels-Alder reaction.”
Science
2010,
329,
309–313.
DOI: 10.1126/science.1190239
13. Hoover, J. M.; DiPasquale, A.; Mayer, J. M.; Michael, F. E.
“Platinum Catalyzed Intramolecular Hydrohydrazination: Evidence for Alkene Insertion into a Pt-N Bond.”
J. Am. Chem. Soc.
2010,
132,
5043–5053.
DOI: 10.1021/ja906563z
12. Lovick, H. M.; Michael, F. E.
“Metal-Free Highly Regioselective Aminotrifluoroacetoxylation of Alkenes.”
J. Am. Chem. Soc.
2010,
132,
1249–1251.
DOI: 10.1021/ja906648w
11. Sibbald, P. A.; Rosewall, C. F.; Swartz, R. D.; Michael, F. E.
“Mechanism of N-Fluorobenzenesulfonimide Promoted Diamination and Carboamination Reactions: Divergent Reactivity of a Pd(IV) Species.”
J. Am. Chem. Soc.
2009,
131,
15945–15951.
DOI: 10.1021/ja906915w
10. Rosewall, C. F.; Sibbald, P. A.; Liskin, D. V.; Michael, F. E.
“Palladium Catalyzed Carboamination of Alkenes Promoted by N-Fluorobenzenesulfonimide via C-H Activation of Arenes.”
J. Am. Chem. Soc.
2009,
131,
9488–9489.
DOI: 10.1021/ja9031659
9. Sibbald, P. A.; Michael, F. E.
“Palladium-Catalyzed Diamination of Unactivated Alkenes Using N-fluorobenzenesulfonimide as a Source of Electrophilic Nitrogen.”
Org. Lett.
2009,
11,
1147–1149.
DOI: 10.1021/ol9000087
8. Lovick, H. M.; Michael F. E.
“Reversal of enantioselectivity using tethered bisguanidine catalysts in the aza-Henry reaction.”
Tetrahedron Lett.
2009,
50,
1016–1019.
DOI: 10.1016/j.tetlet.2008.12.058
7. Cochran, B. M.; Michael, F. E.
“Metal-free Oxidative Cyclization of Urea-Tethered Alkenes with Hypervalent Iodine.”
Org. Lett.
2008,
10,
5039–5042.
DOI: 10.1021/ol8022165
6. Hoover, J. M.; Freudenthal, J.; Michael, F. E.; Mayer, J. M.
“Reactivity of low-valent Ir, Rh, and Pt complexes with di- and tetrasubstituted hydrazines.”
Organometallics
2008,
27,
2238–2245.
DOI: 10.1021/om701192s
5. Sibbald, P. A.; Cochran, B. M.; Michael, F. E.
“Palladium-Catalyzed Intramolecular Chloroamination of Alkenes.”
Org. Lett.
2008,
9,
793–796.
DOI: 10.1021/ol702922c
4. Cochran, B. M.; Michael, F. E.
“Synthesis of 2,6-Disubstituted Piperazines by a Diastereoselective Palladium-Catalyzed Hydroamination Reaction.”
Org. Lett.
2008,
9,
329–332.
DOI: 10.1021/ol702891p
3. Cochran, B. M.; Michael, F. E.
“Mechanistic Studies of a Palladium Catalyzed Intramolecular Hydroamination of Unactivated Alkenes: Protonolysis of a Stable Palladium Alkyl Complex is the Turnover-limiting Step.”
J. Am. Chem. Soc.
2008,
130,
2786–2792.
DOI: 10.1021/ja0734997
2. Hoover, J. M.; DiPasquale, A.; Mayer, J. M.; Michael, F. E.
“Synthesis and Reactivity of a RuIII bis(anilide) Dimer by Oxidative Addition of an N,N′-disubstituted Hydrazine.”
Organometallics
2007,
26,
3397–3405.
DOI: 10.1021/om0700462
1. Michael, F. E.; Cochran, B. M.
“Room-Temperature Palladium-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes.”
J. Am. Chem. Soc.
2006,
128,
4246–4248.
DOI: 10.1021/ja060126h