Prof. Daniel R. Gamelin |
 |
Harry and Catherine Jaynne Boand Endowed Professor in Chemistry |
Education, Research, and Professional Experience
- 2010-present Associate Editor, Chemical Communications
- 2008-present Professor, Department of Chemistry, University of Washington, Seattle, WA
- 07/2008 Invited Visiting Professor, University of Konstanz, Center for Applied Photonics, with Prof.
Alfred Leitenstorfer and Dr. Rudi Bratschitsch
- 07/2008 Invited Visiting Professor, École Polytechnique Fédérale de Lausanne (EPFL), Laboratory for
Photonics and Interfaces, with Prof. Michael Grätzel
- 2000-2008 Assistant/Associate Professor, Department of Chemistry, University of Washington, Seattle, WA
- 1997-2000 Postdoctoral Research Fellow, University of Bern, Bern, Switzerland, with Prof. Hans U. Güdel
- 1998 PhD, Stanford University, Stanford, CA, with Prof. Edward I. Solomon
- 1990-1991 Predoctoral Research Fellow, Max-Planck-Institut für Strahlenchemie, Mülheim an der Ruhr, 4
Germany, with Prof. Friedrich-Wilhelm Grevels
- 1990 B.A., Chemistry, Reed College, Portland, OR
- 1989 NSF-REU, Chemistry, Brandeis University, Waltham, MA
Awards & Honors
- 2013 Debye Chair Professor, Debye Institute for Nanomaterials Science, Utrecht University
- 2013 Jonathan L. Sessler Distinguished Alumni Lecturer, Stanford University, Chemistry
- 2012 ACS Inorganic Nanoscience Award
- 2012 Fellow of the American Association for the Advancement of Science (AAAS)
- 2011–2012 Dalton Transactions Americas Lecturer, U.C. Berkeley
- 2011 Scialog Fellow of the Research Corporation
- 2009
Zukunftskolleg Award (Senior Fellow), University of Konstanz
- 2008–present, Harry and Catherine Jaynne Boand Endowed Professor in Chemistry
- 2008 Ornstein Colloquium Lecturer, Utrecht University
- 2007–2008, Invited Visiting Professor, École Polytechnique Fédérale de
Lausanne (EPFL), Laboratory for Photonics and Interfaces
- 2007–2008, Invited Visiting Professor, University of Konstanz, Center for Applied Photonics
- 2007 Cherry Emerson Seminar, Georgia Tech, Chemistry
- 2006 Sloan Research Fellowship, Alfred P.
Sloan Foundation
- 2005 Camille Dreyfus Teacher-Scholar Award, Dreyfus Foundation
- 2005 Dow Lecturer in Inorganic Chemistry, Caltech
- 2003 Presidential Early Career Award for Scientists and Engineers (PECASE)
- 2003 Cottrell Scholar Award, Research Corporation
- 2003 CAREER Award, National Science Foundation
- 2002 Research Innovation Award, Research Corporation
- 1995 Franklin Veatch Memorial Fellowship Award for excellence in graduate research at Stanford
University
- 1990 Deutscher Akademischer AustauschDienst (DAAD) fellowship for predoctoral research at the
Max-Planck-Institut für Strahlenchemie (Mülheim/Ruhr)
- 1989 NSF-REU Awardee, Brandeis University
PUBLICATIONS
2013
Cohn, A. W.; Schimpf, A. M.; Gunthardt, C. E.; Gamelin, D. R. "Size-Dependent Trap-Assisted Auger
Recombination in Semiconductor Nanocrystals." Nano Letters, 2013, 13, 1810−1815.
(view)
McLaurin, E. J.; Bradshaw, L. R.; Gamelin, D. R. "Dual-Emitting Nanoscale Temperature Sensors." Chem.
Mater., 2013, 25, 1283-1292.(view)
Yang, P.; Zhong, D. K.; Yuan, M.; Rice, A. H.; Gamelin, D. R.; Luscombe, C. K. "TiO2 Nanowire
Electron Transport Pathways inside Organic Photovoltaics." Phys. Chem. Chem. Phys., 2013,
15, 4566−4572. (view)
McLaurin, E. J.; Fataftah, M. S.; Gamelin, D. R. "One-step synthesis of alloyed dual-emitting semiconductor nanocrystals." Chem. Commun., 2013, 49, 39−41. (view)
2012
Gamelin, D. R. "Water splitting: Catalyst or Spectator?" Nature Chemistry (News and
Views), 2012, 4, 965−967. (view)
Schlenker, C. W.; Chen, K.-S.; Yip, H.-L.; Li, C.-Z.; Bradshaw, L. R.; Ochsenbein, S. T.;
Ding, F.; Li, X.; Gamelin, D. R.; Jen, A. K.-Y.; Ginger, D. S. "Polymer triplet energy levels need not limit photocurrent collection in organic solar cells." J. Am. Chem. Soc., 2012, 134, 19661-19668. (view)
Rinehart, J. D.; Weaver, A. L.; Gamelin, D. R. "Redox Brightening of Colloidal Semiconductor Nanocrystals using Molecular Reductants." J. Am. Chem. Soc., 2012, 134, 16175–16177. (view)
Cohn, A. W.; Janßen, N.; Mayer, J. M.; Gamelin, D. R. "Photocharging ZnO Nanocrystals: Picosecond Hole Capture, Electron Accumulation, and Auger Recombination" J. Phys. Chem. C, 2012, 116, 20633−20642. (view)
Schimpf, A. M.; Ochsenbein, S. T.; Buonsanti, R.; Milliron, D. J.; Gamelin, D. R. "Comparison of Extra Electrons in Colloidal n-Type Al3+-Doped and Photochemically Reduced ZnO Nanocrystals" Chem. Commun., 2012, 48, 9352−9354.(view)
Schimpf, A.; Gamelin, D. R. "Thermal Tuning and Inversion of Excitonic Zeeman Splittings in Colloidal Doped CdSe Quantum Dots" J. Phys. Chem. Lett., 2012, 3, 1264-1268. (view)
Cohn, A. W.; Kittilstved, K. R.; Gamelin, D. R. "Tuning the Potentials of "Extra" Electrons in Colloidal n-Type ZnO Nanocrystals via Mg2+ Substitution" J. Am. Chem. Soc., 2012, 134, 7937-7943. (view)
Peng, B.; Liang, W.; White, M. A.; Gamelin, D. R.; Li, X. "Theoretical Evaluation of Spin-Dependent Auger De-excitation in Mn2+-Doped Semiconductor Nanocrystals." J. Phys. Chem. C., 2012, 116, 11223-11231. (view)
Bradshaw, L. R.; Hauser, A.; McLaurin, E. J.; Gamelin, D. R. "Luminescence Saturation via Mn2+-Exciton Cross Relaxation in Colloidal Doped Semiconductor Nanocrystals." J. Phys. Chem. C., 2012, 116, 9300-9310. (view)
Weaver, A. L.; Gamelin, D. R. "Photoluminescence Brightening via Electrochemical Trap Passivation in ZnSe and Mn2+-Doped ZnSe Quantum Dots." J. Am. Chem. Soc., 2012, 134, 6819–6825.
(view)
2011
Beaulac, R.; Feng, Y.; May, J. W.; Badaeva, E.; Gamelin, D. R.; Li, X. "Orbital Pathways for Mn2+-Carrier sp-d Exchange in Magnetic Semiconductor Quantum Dots." Phys. Rev. B, 2011, 84, 195324.
(view)
Zhong, D. K.; Choi, S.; Gamelin, D. R. "Near-Complete Suppression of Surface Recombination in Solar Photoelectrolysis by "Co-Pi" Catalyst-Modified
W:BiVO4." J. Am. Chem. Soc., 2011, 133, 18370–18377.
(view)
Badaeva, E.; May, J. W.; Ma, J.; Gamelin, D. R.; Li, X. "Characterization of Excited-State Magnetic Exchange in Mn2+-doped ZnO Quantum Dots
using Time-Dependent Density Functional Theory." J. Phys. Chem. C, 2011, 115, 20986–20991.
(view)
McLaurin, E. J.; Vlaskin, V. A.; Gamelin, D. R. "Water-Soluble Dual-Emitting Nanocrystals for Ratiometric Optical Thermometry." J. Am. Chem. Soc., 2011, 133, 14978–14980.
(view)
Whitaker, K. M.; Raskin, M.; Kiliani, G.; Beha, K.; Ochsenbein, S. T.; Janßen, N.; Fonin, M.; Rüdiger, U.;
Leitenstorfer, A.; Gamelin, D. R.; Bratschitsch, R. "Spin-on Spintronics: Ultrafast Electron Spin Dynamics in ZnO and Zn
1-xCoxO Sol-Gel Films." Nano Letters, 2011, 11, 335-3360.
(view)
Bacher, G.; Schneider, L.; Beaulac, R.; Archer, P. I.; Gamelin, D. R. "Magnetic Polaron Formation Dynamics in Mn
2+-Doped Colloidal Nanocrystals up to Room Temperature." J. Korean Phys. Soc., 2011,
58, 1261-1266.
(view)
White, M. A.; Weaver, A. L.; Beaulac, R.; Gamelin, D. R. "Electrochemically Controlled Auger Quenching of
Mn2+ Photoluminescence in Doped Semiconductor Nanocrystals." ACS Nano, 2011, 5, 4158-4168.
(view)
Zhong, D. K.; Cornuz, M.; Sivula, K.; Grätzel, M.; Gamelin, D. R. "Photo-assisted electrodeposition of cobalt–phosphate
(Co–Pi) catalyst on hematite photoanodes for solar water oxidation." Energy Environ. Sci., 2011, 4,
1759-1764. (
view)
Hayoun, R.; Whitaker, K. M.; Gamelin, D. R.; Mayer, J. M. "Electron Transfer Between Colloidal ZnO Nanocrystals."
J. Am. Chem. Soc., 2011, 133, 4228-4231. (
view)
Ochsenbein, S. T.; Gamelin, D. R. "Quantum Oscillations in Magnetically Doped Colloidal Nanocrystals." Nature
Nanotechnology, 2011, 6, 112–115. (
view)
2010
Beaulac, R.; Gamelin, D. R. "Two-Center Formulation of Mn2+-Electron s-d Exchange Coupling in Bulk and
Quantum Confined Diluted-Magnetic Semiconductors." Phys. Rev. B, 2010, 82, 224401. (view)
Johnson, C. A.; Kittilstved, K. R.; Kaspar, T. C.; Droubay, T. C.; Chambers, S. A.; Salley, G. M.; Gamelin, D. R. "Mid-Gap Electronic States in Zn1-xMnxO." Phys. Rev. B, 2010, 82, 115202. (view)
Vlaskin, V. A.; Janßen, N.; van Rijssel, J.; Beaulac, R.; Gamelin, D. R. "Tunable Dual Emission in Doped Semiconductor Nanocrystals." Nano Letters, 2010, 10, 3670–3674. (view)
Whitaker, K. M.; Ochsenbein, S. T.; Smith, A. L.; Echodu, D. C.; Robinson, B. H.; Gamelin, D. R. "Hyperfine Coupling in Colloidal n-type ZnO Quantum Dots: Effects on Electron Spin Relaxation." J. Phys. Chem. C, 2010, 114, 14467–14472. (view)
Sun, J.; Zhong, D. K.; Gamelin, D. R. "Composite Photoanodes for Photoelectrochemical Solar Water Splitting." Energy & Env. Science, 2010, 3, 1252–1261. (invited review) (view)
Feng, Y.; Badaeva, E.; Gamelin, D. R.; Li, X. "Excited-State Double Exchange in Manganese-Doped ZnO Quantum Dots: A Time-Dependent Density-Functional Study." J. Phys. Chem. Lett., 2010, 1, 1927-1931. (view)
White, M. A.; Lovejoy, T. C.; Ochsenbein, S. T.; Olmstead, M. A.; Gamelin, D. R. "Sputtering Induced Co0 Formation in X-Ray Photoelectron Spectroscopy of Nanocrystalline Zn1-xCoxO Spinodal Enrichment Models." J. Appl. Phys., 2010, 107, 103917. (view)
Zhong, D. K.; Gamelin, D. R. "Photoelectrochemical Water Oxidation by Cobalt Catalyst ("Co-Pi")/α-Fe2O3 Composite Photoanodes: Oxygen Evolution and Resolution of a Kinetic Bottleneck." J. Am. Chem. Soc., 2010, 132, 4202–4207. (view)
Johnson, C. A.; Kaspar, T. C.; Chambers, S. A.; Salley, G. M.; Gamelin, D. R. "Sub-Bandgap Photoconductivity in Co2+-Doped ZnO." Phys. Rev. B, 2010, 12, 125206. (view)
Beaulac, R.; Ochsenbein, S. T.; Gamelin, D. R. "Colloidal Transition-Metal-Doped Quantum Dots." Chapter 11 in Nanocrystal Quantum Dots. Edited by V. I. Klimov, 2010, Taylor & Francis, New York. (view)
2009
Vlaskin, V. A.; Beaulac, R; Gamelin, D. R. "Dopant-Carrier Magnetic Exchange Coupling in Colloidal Inverted Core/Shell Semiconductor Nanocrystals." Nano Letters, 2009, 9, 4376-4382. (view)
Beaulac, R.; Schneider, L.; Archer, P. I.; Bacher, G.; Gamelin, D. R. "Light-Induced Spontaneous Magnetization in Doped Colloidal Quantum Dots." Science, 2009, 325, 973-976. (view)
Ochsenbein, S. T.; Feng, Y.; Whitaker, K. M.; Badaeva, E.; Liu, W. K.; Li, X.; Gamelin, D. R. "Charge-Controlled Magnetism in Colloidal Doped Semiconductor Nanocrystals." Nature Nanotechnol., 2009, 4, 681-687. (view)
Lee, H. J.; Chen, P.; Moon, S.-J.; Sivula, K.; Besso, T.; Gamelin D. R.; Comte, P.; Zakeeruddin, S. M.; Grätzel, M. & Nazeeruddin, Md. K. "Regenerative PbS and CdS Quantum Dot-Sensitized Solar Cells with a Cobalt Complex as a Hole Mediator." Langmuir, 2009, 25, 7602-7608. (view)
Zhong, D. K.; Sun, J. ; Gamelin, D. R. "Solar Water Oxidation by Composite Catalyst/α-Fe2O3 Photoanodes." J. Am. Chem. Soc., 2009, 131, 6086-6087. (view)
Badaeva, E.; Isborn, C. M.; Feng, Y.; Ochsenbein, S. T.; Gamelin, D. R.; Li, X. "Theoretical Characterization of Electronic Transitions in Co2+- and Mn2+-Doped ZnO Nanocrystals." J. Phys. Chem. C, 2009, 113, 8710-8717. (view)
Droubay, T. C.; Keavney, D. J.; Kaspar, T. C.; Heald, S. M.; Wang, C. M.; Johnson, C. A.; Whitaker, K. M.; Gamelin, D. R.; Chambers, S. A. "Correlated Substitution in Paramagnetic Mn2+-Doped ZnO Epitaxial Films." Phys. Rev. B, 2009, 79, 155203. (view)
2008
White, M. A.; Ochsenbein, S. T.; Gamelin, D. R. "Colloidal Nanocrystals of Wurtzite Zn1-xCoxO (0 < x < 1): Models of Spinodal Decomposition in an Oxide Diluted Magnetic Semiconductor." Chem. Mater., 2008, 20, 7107-7116. (view)
Beaulac, R.; Archer, P. I.; Ochsenbein, S. T.; Gamelin, D. R. "Mn2+-Doped CdSe Quantum Dots: New Inorganic Materials for Spin-Electronics and Spin-Photonics." Advanced Functional Materials, 2008, 18, 3873-3891 (Feature Article). (view)
Beaulac, R.; Archer, P. I.; van Rijssel, J.; Meijerink, A.; Gamelin, D. R. "Exciton Storage by Mn2+ in Colloidal Mn2+-Doped CdSe Quantum Dots." Nano Letters, 2008, 8, 2949-2953. (view)
Whitaker, K. M.; Ochsenbein, S. T.; Polinger, V. Z.; Gamelin, D. R. "Electron Confinement Effects in the EPR Spectra of Colloidal n-Type ZnO Quantum Dots." J. Phys. Chem. C, 2008, 112, 14331-14335. (view)
Thomay, T.; Hanke, T.; Tomas, M.; Sotier, F.; Beha, K.; Knittel, V.; Kahl, M.; Whitaker, K. M.; Gamelin, D. R.; Leitenstorfer, A.; Bratschitsch, R. "Colloidal ZnO Quantum Dots in Ultraviolet Pillar Microcavities." Optics Express, 2008, 16, 9791-9794. (view)
Janssen, N.; Whitaker, K. M.; Gamelin, D. R.; Bratschitsch, R. "Ultrafast Spin Dynamics in Colloidal ZnO Quantum Dots." Nano Letters, 2008, 8, 1991-1994. (view)
Beaulac, R.; Archer, P. I.; Gamelin, D. R."Luminescence in Colloidal Mn2+-Doped Semiconductor Nanocrystals." J. Solid State Chem. 2008, 181, 1585-1592. (view)
Beaulac, R.; Archer, P. I.; Liu, X.; Lee, S.; Salley, G. M.; Dobrowolska, M. ; Furdyna, J. K.; Gamelin, D. R. "Spin-Polarizable Excitonic Luminescence in Colloidal Mn2+-Doped CdSe Quantum Dots." Nano Letters,
2008, 8, 1197-1201. (view)
Badaeva, E.; Feng, Y.; Gamelin, D. R.; Li, X. "Investigation of Pure and Co2+-Doped ZnO Quantum Dot Electronic Structures using Density Functional Theory: Choosing the Right Functional." New J. Phys.,
2008, 10, 055013. (view)
Kaspar, T. C.; Droubay, T.; Li, Y.; Heald, S. M.; Nachimuthu, P.; Wang, C. M.; Shutthanandan, V.; Johnson, C. A.; Gamelin, D. R.; Chambers, S. A. "Lack of Ferromagnetism in n-Type Cobalt-Doped ZnO Epitaxial Thin Films." New J. Phys.,
2008, 10, 055010. (view)
2007
Archer, P. I.; Santangelo, S. A.; Gamelin, D. R. "Inorganic Cluster Syntheses of TM2+-Doped Quantum Dots (CdSe, CdS, CdSe/CdS): Physical Property Dependence on Dopant Locale." J. Am. Chem. Soc., 2007, 129, 9808-9818. (view)
Liu, W. K.; Whitaker, K. M.; Smith, A. L.; Kittilstved, K. R.; Robinson, B. H.; Gamelin, D. R. "Room-Temperature Electron Spin Dynamics in Free-Standing ZnO Quantum Dots." Phys. Rev. Lett., 2007, 98, 186804. (view)
Archer, P. I.; Santangelo, S. A.; Gamelin, D. R. "Direct Observation of sp-d Exchange Interactions in Colloidal Mn2+- and Co2+-Doped CdSe Quantum Dots." Nano Letters, 2007, 7, 1037-1043. (view)
Santangelo, S. A.; Hinds, E. A.; Vlaskin, V. A.; Archer, P. I.; Gamelin, D. R. "Bimodal Bond-Length Distributions in Cobalt-Doped CdSe, ZnSe, and Cd1-xZnxSe Quantum Dots." J. Am. Chem. Soc., 2007, 129, 3973-3978. (view)
Chambers, S. A.; Schwartz, D. A.; Liu, W. K.; Kittilstved, K. R.; Gamelin, D. R. " Growth, Electronic and Magnetic Properties of Doped ZnO Epitaxial and Nanocrystalline Films. " Appl. Phys. A,
2007, 88, 1-5. (Invited Paper) (view)
Archer, P. I.; Gamelin, D. R. "Chemical Approaches using Nanocrystals to Control Lattice Defect Formation and Explore the High-TC Ferromagnetism of Oxide Diluted Magnetic Semiconductors." Chapter in Magnetism in New Semiconducting and Insulating Oxides, edited by N. H. Hong,
2007, Research Signpost Press. (Invited Review)
2006
Norberg, N. S.; Dalpian, G. M.; Chelikowsky, J. R.; Gamelin, D. R. "Energetic Pinning of Magnetic Impurity Levels in Quantum Confined Semiconductor Nanocrystals." Nano Letters, 2006, 6, 2887-2892. (view)
Chambers, S. A.; Droubay, T. C.; Wang, C. M.; Rosso, K.; Heald, S. M.; Schwartz, D. A.; Kittilstved, K. R.; Gamelin, D. R. "Ferromagnetism in Oxide Semiconductors?" Materials Today, 2006, 9, 28-35. (Invited Review) (view)
Norberg, N. S.; Parks, G. L.; Salley, G. M.; Gamelin, D. R. "Giant Excitonic Zeeman Splittings in Colloidal Co2+-Doped ZnSe Quantum Dots." J. Am. Chem. Soc., 2006, 128, 13195-13203. (view)
Kittilstved, K. R.; Zhao, J.; Liu, W. K.; Bryan, J. D.; Schwartz, D. A.; Gamelin, D. R. "Magnetic Circular Dichroism of Ferromagnetic Co2+-Doped ZnO." Appl. Phys. Lett., 2006, 89, 062510. (view)
Kittilstved, K. R.; Schwartz, D. A.; Tuan, A. C.; Heald, S. M.; Chambers, S. A.; Gamelin, D. R. "Direct Kinetic Correlation of Carriers and Ferromagnetism in Co2+:ZnO." Phys. Rev. Lett., 2006, 97, 037203. (view)
Kaspar, T. C.; Droubay, T.; Shutthanandan, V.; Heald, S. M.; Wang, C. M.; McCready, D. E.; Thevuthasan, S.; Bryan, J. D.; Gamelin, D. R.; Kellock, A. J.; Toney, M. F.; Hong, X.; Ahn, C. H.; Chambers, S. A. "Ferromagnetism and Structure of Epitaxial Cr-Doped Anatase TiO2 Thin Films." Phys. Rev. B, 2006, 73, 155327. (view)
Kittilstved, K. R.; Liu, W. K.; Gamelin, D. R. "Electronic Structure Origins of Polarity Dependent High-TC Ferromagnetism in Oxide Diluted Magnetic Semiconductors." Nature Materials, 2006, 5, 291-297. (view)
Liu, W. K.; Whitaker, K. M.; Kittilstved, K. R.; Gamelin, D. R. "Stable Photogenerated Carriers in Magnetic Semiconductor Nanocrystals ." J. Am. Chem. Soc., 2006, 128, 3910-3911. (view)
Kittilstved, K. R.; Gamelin, D. R. "Manipulating Polar Ferromagnetism in Transition Metal Doped ZnO: Why Manganese is Different from Cobalt." J. Appl. Phys., 2006, 99, 08M112. (Invited Paper) (view)
Archer, P. I.; Gamelin, D. R. "Controlled Grain-Boundary Defect Formation and its Role in the High-TC Ferromagnetism of Ni2+:SnO2." J. Appl. Phys., 2006, 99, 08M107. (view)
Norberg, N. S.; Gamelin, D. R. "Giant Zeeman Effects in Colloidal Diluted Magnetic Semiconductor Quantum Dots with Homogeneous Dopant Speciation." J. Appl. Phys., 2006, 99, 08M104. (view)
2005
Kaspar, T.C.; Heald, S.M.; Wang, C.M.; Bryan, J. D.; Droubay, T.; Shutthanandan, V.; Thevuthasan, S.; McCready, D.E.; Kellock, A.J.; Gamelin, D. R.; Chambers, S.A. "Negligible Magnetism in Excellent Structural Quality Crx:Ti1-xO2 Anatase: Contrast with High-TC Ferromagnetism in Structurally Defective Crx:Ti1-xO2." Phys. Rev. Lett., 2005, 95, 217203. (view)
Norberg, N. S.; Gamelin, D. R. "Influence
of Surface Modification on the Luminescence of Colloidal ZnO Nanocrystals."
J. Phys. Chem. B, 2005, 109, 20810-20816. (view)
Bryan, J. D.; Santangelo, S. A.; Keveren, S. C.;
Gamelin, D. R. "Activation of High-TC Ferromagnetism in
Co2+:TiO2 and Cr3+:TiO2 Nanorods
and Nanocrystals by Grain Boundary Defects." J. Am. Chem. Soc.,
2005,
127, 15568-15574. (view)
Archer, P. I.; Radovanovic, P. V.; Heald, S. M.;
Gamelin, D. R. "Low-Temperature Activation and Deactivation of High-TC
Ferromagnetism in a New Diluted Magnetic Semiconductor: Ni2+-Doped
SnO2." J. Am. Chem. Soc.,
2005, 127, 14479-14487. (view)
Liu, W. K.; Salley, G. M.; Gamelin, D. R. "Spectroscopy
of Photovoltaic and Photoconductive Nanocrystalline Co2+-doped
ZnO Electrodes." J. Phys. Chem. B, 2005, 109, 14486-14495. (view)
Kittilstved, K. R.; Norberg, N. S.; Gamelin, D.
R. "Chemical Manipulation of High-TC Ferromagnetism in
ZnO Diluted Magnetic Semiconductors." Phys. Rev. Lett., 2005, 94,
147209. (view)
Kittilstved, K. R.; Gamelin, D. R. "Activation
of High-TC Ferromagnetism in Mn2+:ZnO using Amines."
J. Am. Chem. Soc., 2005, 127, 5292-5293. (view)
Bryan, J. D.; Schwartz, D. A.; Gamelin, D. R. "The
Influence of Dopants on the Nucleation of Semiconductor Nanocrystals from
Homogeneous Solution " J. Nanosci. Nanotech., 2005, 5,
1472-1479. (Invited Paper) (view)
Bryan, J. D.; Gamelin, D. R. "Doped Semiconductor
Nanocrystals: Synthesis, Characterization, Physical Properties, and Applications"
Progress in Inorganic Chemistry, 2005, 54, 47-126. (Invited Review) (view)
2004
Schwartz, D. A.; Gamelin, D. R. "Reversible
300K Ferromagnetic Ordering in a Diluted Magnetic Semiconductor"
Advanced Materials, 2004, 16, 2115-2119. (view)
Schwartz, D. A.; Kittilstved, K. R.; Gamelin, D.
R. "Above-Room-Temperature Ferromagnetic Ni2+:ZnO Thin
Films Prepared from Colloidal Diluted Magnetic Semiconductor Quantum Dots"
Appl. Phys. Lett., 2004, 85, 1395-1397. (view)
Bryan, J. D.; Heald, S. M.; Chambers, S. A.; Gamelin,
D. R. "h8 Room-Temperature Ferromagnetism in Co2+-Doped
TiO2 made from Colloidal Nanocrystals" J. Am. Chem. Soc.,
2004, 126, 11640-11647. (view)
Tuan, A.; Bryan, J. D.; Pakomov, A.; Shutthanandan,
V.; Thevuthasan, S.; McCready, D.; Gaspar, D.; Engelhard, M.; Rogers,
Jr., J. W.; Krishnan, K.; Gamelin, D. R.; Chambers S. A.; "Epitaxial
Growth and Properties of Cobalt-doped ZnO on α-Al2O3
Single Crystal Substrates" Phys. Rev. B,
2004, 70, 054424. (view)
Norberg, N. S.; Kittilstved, K. R.; Amonette, J.
E.; Kukkadapu, R. K.; Schwartz, D. A.; Gamelin, D. R. "Synthesis
of Colloidal Mn2+:ZnO Quantum Dots and High-TC Ferromagnetic
Nanocrystalline Thin Films" J. Am. Chem. Soc., 2004, 126, 9387-9398. (view)
2003
Schwartz, D. A.; Gamelin, D. R. "A Simple
Room-Temperature Preparation of Colloidal ZnO Quantum Dots from Homogeneous
Polar Aprotic Solutions" Proc. SPIE-Int. Soc. Opt. Eng., 2003, 5224,
1-7. (Invited Paper) (view)
Radovanovic, P. V.; Gamelin, D. R. "High-Temperature
Ferromagnetism in Ni2+-doped ZnO Aggregates Prepared from Colloidal
Diluted Magnetic Semiconductor Quantum Dots" Phys. Rev. Lett., 2003,
91, 157202/1-4. (view)
Schwartz, D. A.; Norberg, N. S.; Nguyen, Q. P.;
Parker, J. M.; Gamelin, D. R. "Magnetic Quantum Dots: Synthesis,
Spectroscopy, and Magnetism of Co2+- and Ni2+-Doped
ZnO Nanocrystals" J. Am. Chem. Soc., 2003, 125, 13205-13218. (view)
2002
Radovanovic, P. V.; Norberg, N. S.; McNally, K.
E.; Gamelin, D. R. "Colloidal Transition-Metal-Doped ZnO Quantum
Dots" J. Am. Chem. Soc., 2002, 124, 15192-15193. (view)
Radovanovic, P. V.; Gamelin, D. R. "Isocrystalline
Core/Shell Synthesis of High Quality II-VI Diluted Magnetic Semiconductor
Quantum Dots: Ligand Field Spectroscopic Studies" Proc. SPIE-Int.
Soc. Opt. Eng., 2002, 4807, 223-231. (view)
Radovanovic, P. V.; Gamelin, D. R. "Magnetic
Circular Dichroism Spectroscopy of Co2+:CdS diluted Magnetic
Semiconductor Quantum Dots" Proc. SPIE-Int. Soc. Opt. Eng., 2002,
4809, 51-61. (view)
2001
Radovanovic, P. V.; Gamelin, D. R. "Electronic
Absorption Spectroscopy of Cobalt Ions in Diluted Magnetic Semiconductor
Quantum Dots: Demonstration of an Isocrystalline Core/Shell Synthetic
Method" J. Am. Chem. Soc., 2001, 123, 12207-12214. (view)
2000
Gamelin, D. R.; Güdel, H. U. "Excited-State
Dynamics and Sequential Two-Photon Upconversion Excitation of Mo3+-Doped
Chloro- and Bromo-Elpasolites" J. Phys. Chem. B, 2000, 104, 11045-11057.
Wenger, O. S.; Gamelin, D. R.; Güdel, H. U.
"Chemical Manipulation of Ni2+ Upconversion through Magnetic
Exchange Interactions" J. Am. Chem. Soc., 2000, 122, 7408-7409.
Gamelin, D. R.; Lüthi, S. R.; Güdel,
H. U. "The Role of Laser Heating in the Intrinsic Optical Bistability
of Yb3+-Doped Bromide Lattices" J. Phys. Chem. B, 2000,
104, 10222-10234.
Brunold, T. C.; Gamelin, D. R.; Solomon, E. I.
"Excited-State Exchange Coupling in Bent Mn(III)-O-Mn(III) Complexes:
Dominance of the π/σ
Superexchange Pathway and Its Possible Contributions to the Reactivities
of Binuclear Metalloproteins" J. Am. Chem. Soc., 2000, 122, 8511-8523.
Gamelin, D. R.; Güdel, H. U. "Upconversion
Processes in Transition Metal and Rare Earth Metal Systems" Topics
in Current Chemistry, 2000
, 214, 1-56. (review)
Wenger, O. S.; Gamelin, D. R.; Güdel, H. U.;
Butashin, A. V.; Kaminskii, A. A. "Site-Selective Yellow to Violet
and Near-Infrared to Green Upconversion in BaLu2F8:Nd3+"
Phys. Rev. B, 2000, 61, 16530-16537.
Gamelin, D. R.; Güdel, H. U. "Design
of Luminescent Inorganic Materials: New Photophysical Processes studied
by Optical Spectroscopy" Acct. Chem. Res., 2000, 33, 235-242.
Pollnau, M.; Gamelin, D. R.; Luthi, S. R.; Güdel,
H. U.; Hehlen, M. P. "Power Dependence of Upconversion Luminescence
in Lanthanide and Transition-Metal-Ion Systems" Phys. Rev. B, 2000,
61, 3337-3346.
Randall, D. W.; Gamelin, D. R.; LaCroix, L. B.;
Solomon, E. I. "Electronic Structure Contributions to Electron Transfer
in Blue Cu and CuA" J. Biol. Inorg. Chem., 2000, 5, 16-29.
1999
Gamelin, D. R.; Wermuth, M.; Güdel, H. U.
"Upconversion Processes of 5d Transition Metal Ions in Crystals"
J. Lumin., 1999, 83-84, 405-410.
Gamelin, D. R.; Güdel, H. U. "Spectroscopy
and Dynamics of Re4+ Near-IR-to-Visible Luminescence Upconversion"
Inorg. Chem., 1999, 38, 5154-5164.
Wenger, O. S.; Gamelin, D. R.; Güdel, H. U.;
Butashin, A. V.; Kaminskii, A. A. "Site-Selective Optical Spectroscopy
and Upconversion Mechanisms of the Laser Material BaLu2F8:Er3+"
Phys. Rev. B, 1999, 60, 5312-5320.
1998
Gamelin, D. R.; Güdel, H. U. "Two-Photon
Spectroscopy of Transition Metals: Near-IR-to-Visible Upconversion Luminescence
by Re4+ and Mo3+" J. Am. Chem. Soc., 1998,
120, 12143-12144.
Brunold, T. C.; Gamelin, D. R.; Stemmler, T. L.;
Penner-Hahn, J. E.; Armh8, W. E.; Solomon, E. I. "Spectroscopic
Studies of Oxidized Manganese Catalase and m-oxo-bridged
Dimanganese(III) Model Complexes: Electronic Structure of the Active Site
and its Relation to Catalysis" J. Am. Chem. Soc., 1998, 120, 8724–8738.
Gamelin, D. R.; Randall, D. W.; Hay, M. T.; Houser,
R. P.; Mulder, T. C.; Canters, G. W.; de Vries, S.; Tolman, W. B.; Lu,
Y.; Solomon, E. I. "Electronic Spectroscopy of Mixed-Valence CuA-Type
Centers: Ligand-Field Control of Ground-State Properties Related to Electron
Transfer" J. Am. Chem. Soc., 1998, 120, 5246–5263.
1997
Hay, M. T.; Ang, M. C.; Gamelin, D. R.; Solomon,
E. I.; Antholine, W. E.; Blackburn, N. J.; Massey, P. D.; Kwon, A. H.;
Lu, Y. "Spectroscopic Characterization of an Engineered Purple CuA
Center in Azurin" Inorg. Chem., 1998, 37, 191–198.
Williams, K. R.; Gamelin, D. R.; LaCroix, L. B.;
Houser, R. P.; Tolman, W. B.; Mulder, T. C.; de Vries, S.; Hedman, B.;
Hodgson, K. O.; Solomon, E. I. "The Influence of Copper-Sulfur Covalency
and Copper-Copper Bonding on Valence Delocalization and Electron Transfer
in the CuA Site of Cytochrome c Oxidase" J. Am. Chem.
Soc., 1997, 119, 613–614.
1996
Gamelin, D. R.; Bominaar, E. L.; Kirk, M. L.; Wieghardt,
K.; Solomon, E. I. "Excited-State Contributions to Ground-State Properties
of Mixed-Valence Dimers: Spectral and Electronic-Structural Studies of
[Fe2(OH)3(tmtacn)2]2+ Related
to the [Fe2S2]+ Active Sites of Plant-Type
Ferredoxins" J. Am. Chem. Soc., 1996, 118, 8085–8097.
Gamelin, D. R.; Bominaar, E. L.; Mathonière,
C.; Kirk, M. L.; Wieghardt, K.; Girerd, J.-J.; Solomon, E. I. "Excited-State
Distortions and Electron Delocalization in Mixed-Valence Dimers: Vibronic
Analysis of the Near-IR Absorption and Resonance Raman Profiles of [Fe2(OH)3(tmtacn)2]2+"
Inorg. Chem., 1996, 35, 4323–4335.
1995
Solomon, E. I.; Kirk, M. L.; Gamelin, D. R.; Pulver,
S. "Bioinorganic Spectroscopy" Methods in Enzymology, 1995, 246, 71–110. (review)
1994
Gamelin, D. R.; Kirk, M. L.; Stemmler, T. L.; Pal,
S.; Armstrong, W. H.; Penner-Hahn, J. E.; Solomon, E. I. "Electronic
Structure and Spectroscopy of Manganese Catalase and Di-μ-oxo
[MnIIIMnIV]
Model Complexes" J. Am. Chem. Soc., 1994, 116, 2392–2399.
Gamelin, D. R.; George, M. W.; Glyn, P.; Grevels,
F.-W.; Johnson, F. P. A.; Klotzbücher, W.; Morrison, S. L.; Russel,
G.; Schaffner, K.; Turner, J. J. "Structural Investigation of the
Ground and Excited States of ClRe(CO)3(4,4'-bipyridyl)2
Using Vibrational Spectroscopy" Inorg. Chem., 1994, 33, 3246–3250.
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