Dr. Matthew Smith
Office: CHB 218
Email: msmith1@uw.edu
Education
- 2019 Ph.D. Chemistry, Stanford University, with Prof. Hemamala I. Karunadasa
- 2013 B.S. in Chemistry, Haverford College, with Profs. Alexander J. Norquist and Joshua Schrier
Awards & Honors
- 2018 - 2020 Mistletoe Research Foundation Fellow
- 2017 - 2020 Center for Molecular Analysis and Design Fellow
- 2009 - 2013 National Science Foundation Graduate Research Fellow
Publications
2019
Crane, M. J.; Kroupa, D.; Roh, J. Y. D.; Anderson, R. T.; Smith, M. D.; Gamelin, D. R. "Single-Source Vapor Deposition of Quantum-Cutting Yb3+:CsPb(Cl1-XBrx)3 and Other Complex Metal-Halide Perovskites." ACS Appl. Energy Mater. 2019, 2, 4560-4565. (view)
Smith, M. D.; Connor, B. A.; Karunadasa, H. I. "Tuning the Luminescence of Layered Halide Perovskites." Chemical Reviews 2019, in press.
2018
Connor, B. A.; Leppert, L.; Smith, M. D.; Neaton, J. B.; Karunadasa, H. I. "Layered Halide Double Perovskites: Dimensional Reduction of Cs2AgBiBr6." Journal of the American Chemical Society 2018, 140, 5235-5240.
Smith, M. D.; Crace, E. C.; Jaffe, A; Karunadasa, H. I. "The Diversity of Layered Halide Perovskites." Annual Review of Materials Research 2018, 48, 111-136.
Smith, M. D.; Karunadasa, H.I. "White-Light Emission from Layered Halide Perovskites." Accounts of Chemical Research 2018, 51, 619-627.
Guzelturk, B.; Belisle, R. A.; Smith, M. D.; Bruening, K.; Prasanna, R.; Yuan, Y.; Gopalan, V.; Tassone, C. J.; Karunadasa, H. I.; McGehee, M. D.; Lindenberg, A. M. "Terahertz Emission from Hybrid Perovskites Driven by Ultrafast Charge Separation and Strong Electron–Phonon Coupling." Advanced Materials 2018, 30, 1704737.
Xu, R. J.; Olshansky, J. H.; Adler, P. D. F.; Huang, Y.; Smith, M. D.; Zeller, M.; Schrier, J.; Norquist, A. J. "Understanding Structural Adaptability: a Reactant Informatics Approach to Experiment Design." Molecular Systems Design and Engineering. 2018, 3, 473-484.
2017
Smith, M. D.; Watson, B. L.; Dauskardt, R. H.; Karunadasa, H. I. "Broadband Emission with a Massive Stokes Shift from Sulfonium Pb–Br Hybrids." Chemistry of Materials 2017, 29, 7083-7087.
Wu, X.; Tan, L. Z.; Shen, X.; Hu, T.; Miyata, K.; Trinh, M. T.; Li, R.; Coffee, R.; Liu, S.; Egger, D. A.; Makasyuk, I.; Zheng, Q.; Fry, A.; Robinson, J. S.; Smith, M. D.; Guzelturk, B.; Karunadasa, H. I.; Wang, X.; Zhu, X.; Kronik, L.; Rappe, A. M.; Lindenberg, A. M. "Light-Induced Picosecond Rotational Disordering of the Inorganic Sublattice in Hybrid Perovskites." Science Advances 2017, 3, e1602388.
Smith, M. D.; Jaffe, A.; Dohner, E. R.; Lindenberg, A. M.; Karunadasa, H. I. "Structural Origins of Broadband Emission from Layered Pb–Br Hybrid Perovskites." Chemical Science 2017, 8, 4497-4504.
Smith, I. C.; Smith, M. D.; Jaffe, A.; Lin, Y.; Karunadasa, H. I. "Between the Sheets: Postsynthetic Transformations in Hybrid Perovskites." Chemistry of Materials 2017, 29, 1868-1884.
Smith, M. D.; Pedesseau, L.; Kepenekian, M.; Smith, I. C.; Katan, C.; Even, J.; Karunadasa, H. I. "Decreasing the Electronic Confinement in Layered Perovskites through Intercalation." Chemical Science 2017, 8, 1960-1968.
Jin, Z; Teo, Y. C.; Zulaybar, N. G.; Smith, M. D.; Xia, Y. "Streamlined Synthesis of Polycyclic Conjugated Hydrocarbons Containing Cyclobutadienoids via C–H Activated Annulation and Aromatization." Journal of the American Chemical Society 2017, 139, 1806-1809.
2016
Mercer, J. A. M.; Cohen, C. M.; Shuken, S. R.; Wagner, A. M.; Smith, M. W.; Moss, F. R.; Smith, M. D.; Vahala, R.; Gonzalez-Martinez, A.; Boxer, S. G.; Burns, N. Z. "Chemical Synthesis and Self-Assembly of a Ladderane Phospholipid." Journal of the American Chemical Society 2016, 138, 15845-15848.
Adler, P. D. F.; Xu, R.; Olshansky, J. H.; Smith, M. D.; Elbert, K. C.; Yang, Y.; Ferrence, G. M.; Zeller, M.; Schrier, J.; Norquist, A. J. "Probing Structural Adaptability in Templated Vanadium Selenites." Polyhedron, 2016, 114, 184-193.
Hu, T.; Smith, M. D.; Dohner, E. R.; Sher, M.-J.; Wu, X.; Trinh, M. T.; Fisher, A.; Corbett, J.; Zhu, X.-Y.; Karunadasa, H. I.; Lindenberg, A. M. "Mechanism for Broadband White-Light Emission From Two-Dimensional (110) Hybrid Perovskites." The Journal of Physical Chemisty Letters 2016, 7, 2258-2263.
2015
Martin-Noble, G. C.; Reilley, D.; Rivas, L. M.; Smith, M. D.; Schrier, J. "EQeq plus C: An Empirical Bond-Order-Corrected Extended Charge Equilibration Method." Journal of Chemical Theory and Computation 2015, 11, 3364-3374.
Nourmahnad, A.; Smith, M. D.; Zeller, M.; Ferrence, G. M.; Schrier, J.; Norquist, A. J. "Role of Noncovalent Interactions in Vanadium Tellurite Chain Connectivities." Inorganic Chemistry 2015, 54, 694-703.
2014
Olshansky, J. H.; Wiener, K. J.; Smith, M. D.: Nourmahnad, A.; Charles, M. J.; Zeller, M.; Schrier, J.; Norquist, A. J. "Formation Principles for Vanadium Selenites: The Role of pH on Product Composition." Inorganic Chemistry 2014, 53, 12027-12035.
2013
Chang, K. B.; Smith, M. D.; Zeller, M.; Norquist, A. J. "catena-poly[2,2’,2”-nitrilotris(ethan-aminium)[tri-μ-oxido-tris[dioxidovanadate(V)]] monohydrate]." Acta Crystallographica, Section E. 2013, 69, m570-m571.
Koffer, J. H.; Olshansky, J. H.; Smith, M. D.; Hernandez, K. J.; Zeller, M.; Ferrence, G. M.; Schrier, J.; Norquist, A. J. "Formation Principles for Templated Vanadium Selenite Oxalates." Crystal Growth and Design 2013, 13, 4504-4511
Chang, K.B.; Smith, M. D.; Glor, E. C. Blau, S. M.; Zeller, M.; Schrier, J.; Norquist, A. J. "Steric-Induced Layer Flection in Organically Templated Vanadium Tellurites." Crystal Growth and Design 2013, 13, 2190-2197.
2012
Smith, M. D.; Blau, S. M.; Chang, K. B.; Tran, T.T.; Zeller, M.; Halasyamani, P.S.; Schrier, J.; Norquist, A.J. "Inducing Polarity in [VO3]nn- Chain Compounds Using Asymmetric Hydrogen-Bonding Networks." Journal of Solid State Chemistry. 2012, 195, 86-93.
2011
Smith, M. D.; Blau, S. M.; Chang, K. B.; Zeller, M.; Norquist, A.J. "Beyond Charge Density Matching: The Role of C—H···O Interactions in the Formation of Templated Vanadium Tellurites." Crystal Growth and Design 2011, 11, 4213-4219.