CENTC Publications

Publications

213. Brereton, K. R.; Bellows, S. M.; Fallah, H.; Lopez, A. A.; Adams, R. M.; Miller, A. J. M.; Jones, W. D.; Cundari, T. R. “Aqueous Hydricity from Calculations of Reduction Potential and Acidity in Water”, J. Phys. Chem. B., 2016, 120, 12911-12919.
(DOI: 10.1021/acs.jpcb.6b09864)

212. Kumar, A.; Hackenberg, J. D.; Zhou, G. Steffens, A. M.; Mironov, O.; Saxton, R. J.; Goldman, A. S. “High Yields of Piperylene in the Transfer Dehydrogenation of Pentane Catalyzed by Pincer-ligated Iridium Complexes”, J. Mol. Catal. A, 2017, 426, 368-375.
(DOI: 10.1016/j.molcata.2016.10.019)

211. Brereton, K. R.; Pitman, C. L.; Cundari, T. R.; Miller, A. J. M. “Solvent-Dependent Thermochemistry of an Iridium/Ruthenium H2 Evolution Catalyst”, Inorg. Chem., 2016, 55, 12042-12051.
(DOI: acs.inorgchem.6b02223)

210. Sues, P. E.; John, J. M.; Bukhryakov, K. V.; Schrock, R. R.; Muller, P. “Molybdenum and Tungsten Alkylidene Complexes That Contain a 2-Pyridyl-Substituted Phenoxide Ligand”, Organometallics, 2016, 35, 3587-3593.
(DOI: 10.1021/acs.organomet.6b00644)

209. Peacock, D. M.; Roos, C. B.; Hartwig, J. F. “Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile”, ACS Cent. Sci., 2016, 2, 647-652.
(DOI: 10.1021/acscentsci.6b00187)

208. Goldberg, J. M.; Cherry, S. D. T.; Guard, L. M.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. “Hydrogen Addition to (pincer)IrI(CO) Complexes: The Importance of Steric and Electronic Factors”, Organometallics, 2016, 35, 3546-3556.
(DOI: 10.1021/acs.organomet.6b00598)

207. Connor, G. P.; Holland, P. L. “Coordination Chemistry Insights into the Role of Alkali Metal Promoters in Dinitrogen Reduction”, Catalysis Today, 2016, in press.
(DOI: 10.1016/j.cattod.2016.08.014)

206. Brewster, T. P., Tran, J. C., Heinekey, D. M., Goldberg, K. I. "High Catalytic Efficiency Combined with High Selectivity for the Aldehyde-Water Shift using ( para -cymene)Ruthenium Precatalysts", ACS Catal., 2016, 6, 6302-6305.
(DOI: 10.1021/acscatal.6b02130)

205. Rezayee, N. M.; Samblanet, D. C.; Sanford, M. S. “Iron-Catalyzed Hydrogenation of Amides to Alcohols and Amines”, ACS Catal., 2016, 6, 6377-6383.
(DOI: 10.1021/acscatal.6b01454)

204. Lindley, B. M.; Appel, A. M.; Krogh-Jespersen, K.; Mayer, M. J.; Miller, A. J. M. “Evaluating the Thermodynamics of Electrocatalytic N2 Reduction in Acetonitrile”, ACS Energy Lett., 2016, 1, 698-704.
(DOI: 10.1021/acsenergylett.6b00319)

203. Wyvratt, B. M.; Gaudet, J. R.; Pardue, D. B.; Marton, A.; Rudic, S.; Mader, E. A.; Cundari, T. R.; Mayer, J. M.; Thompson, L. T. “Reactivity of Hydrogen On and In Nanostructured Molybdenum Nitride: Crotonaldehyde Hydrogenation”, ACS Catal., 2016, 6, 5797-5806.
(DOI: 10.1021/acscatal.6b00936)

202. Lotz, M. D.; Camasso, N. M.; Canty, A. J.; Sanford, M. S. “Role of Silver Salts in Palladium-Catalyzed Arene and Heteroarene C–H Functionalization Reactions”, Organometallics2016, in press.
(DOI: 10.1021/acs.organomet.6b00437)

201. Munjanja, L.; Torres-Lopez, C.; Brennessel, W. W.; Jones, W. D. “C–CN Bond Cleavage Using Palladium Supported by a Dippe Ligand”, Organometallics201635, 2010-2013.
(DOI: 10.1021/acs.organomet.6b00304)

200. Pitman, C. L.; Finster, O. N. L.; Miller, A. J. M. "Cyclopentadiene-Mediated Hydride Transfer from Rhodium Complexes.” Chem. Commun.,2016, 52, 9105-9108.
(DOI: 10.1039/C6CC00575F)

199. Bezier, D., Brookhart, M.,“Transfer Dehydrogenations of Alkanes and Related Reactions using Iridium Pincer Complexes“ in C-H Bond Activation and Catalytic Functionalization II, Topics in Organometallic Chemistry, Eds. Dixneuf, P.H., Doucet, H., Springer, 2016.
(DOI: 10.1007/3418_2015_132)

198. Kumar, A.; Goldman, A. S. "Recent Advances in Alkane Dehydrogenation Catalyzed by Pincer Complexes" In Top. Organomet. Chem., van Koten, G., Gossage, R. A., Eds.; Springer International Publishing, 2016; Vol. 54, p 307-334. 
(DOI: 10.1007/3418_2015_113)

197. Yao, W.; Jia, X.; Leng, X.; Goldman, A. S.; Brookhart, M.; Huang, Z. "Catalytic Alkane Transfer-Dehydrogenation by PSCOP Iridium Pincer Complexes", Polyhedron2016, 116, 12-19.
(DOI: 10.1016/j.poly.2016.02.044)

196. Wilklow-Marnell, M.; Brennessel, W. W.; Jones, W. D. "Formation of 5-Membered Metallacycles at iPrPCPIr by C–H, O–H, and C–CO Bond Cleavage", Polyhedron2016, 116, 38-46.
(DOI: /10.1016/j.poly.2016.03.018)

195. Dinh, L. V.; Li, B.; Kumar, A.; Schinski, W.; Field, K. D.; Kuperman, A.; Celik, F. E.; Goldman, A. S. "Alkyl-Aryl Coupling Catalyzed by Tandem Systems of Pincer-Ligated Iridium Complexes and Zeolites", ACS Catal.2016, 6, 2836-2841.
(DOI: 10.1021/acscatal.6b00149)

194. Brewster, T.P.; Rezayee, N.M.; Culakova, Z.; Sanford, M.S.; Goldberg, K.I., “Base Free Iridium-Catalyzed Hydrogenation of Esters and Lactones”, ACS Catal.20166, 3113-3117.
(DOI: 10.1021/acscatal.6b00263)

193. Cook, A. K.; Schimler, S. D.; Matzger, A. J.; Sanford, M. S. "Catalyst-controlled Selectivity in the C–H Borylation of Methane and Ethane", Science2016351, 1421-1424.
(DOI: 10.1126/science.aad9289)

192. Walden, A. G.; Kumar, A.; Lease, N.; Goldman, A. S.; Miller, A. J. M. " Electrochemical and Chemical Routes to Hydride Loss from an Iridium Dihydride", Dalton Trans.2016, 45, 9766-9769.
(DOI: 10.1039/C6DT00522E)

191. Sues, P. E.; John, J. M.; Schrock, R. R.; Muller, P. "Molybdenum and Tungsten Alkylidene and Metallacyclobutane Complexes That Contain a Dianionic Biphenolate Pincer Ligand",  Organometallics2016, 35, 758-761.
(DOI:10.1021/acs.organomet.5b00976)

190. Xu, R.; Chakraborty, S.; Bellows, S. M.; Yuan, H.; Cundari, T. R.; Jones, W. D. " Iron-Catalyzed Homogeneous Hydrogenation of Alkenes under Mild Conditions by a Stepwise, Bifunctional Mechanism", ACS Catal.20166, 2127-2135.
(DOI: 10.1021/acscatal.5b02674)

189. Gallo, J. M. R.; Alamillo, R.; Dumesic, J. A. "Acid-Functionalized Mesoporous Carbons for the Continuous Production of 5-Hydroxymethylfurfural", J. Mol. Catal. A: Chem.2016, 422, 13-17.
(DOI: 10.1016/j.molcata.2016.01.005)

188. Chen, Y.; Choi, S.; Thompson, L. T. "Low Temperature CO2 Hydrogenation to Alcohols and Hydrocarbons over Mo2C Supported Metal Catalysts", J. Catal., 2016, 343, 147-156.
(DOI: 10.1016/j.jcat.2016.01.016)

187. Bezier, D.; Guan, C.; Krogh-Jespersen, K.; Goldman, A. S.; Brookhart, M. "Experimental and Computational Study of Alkane Dehydrogenation Catalyzed by a Carbazolide-Based Rhodium PNP Pincer Complex", Chem. Sci., 2016, 7, 2579-2586.
(DOI: 10.1039/C5SC04794C)

186. Pitman, C. L.; Brereton, K. R.; Miller, A. J. M. "Aqueous Hydricity of Late Metal Catalysts as a Continuum Tuned by Ligands and the Medium"  J. Am. Chem. Soc., 2016, 138, 2252-2260.
(DOI: 10.1021/jacs.5b12363)

185. Kulkarni, A.; Kumar, A.; Goldman, A. S.; Celik, F. E. "Selectivity for Dimers in Pentene Oligomerization over Acid Zeolites", Catalysis Commun., 2016, 75, 98-102.
(DOI: 10.1016/j.catcom.2015.11.012)

184. Wang, D. Y.; Choliy, Y.; Haibach, M. C.; Hartwig, J. F.; Krogh-Jespersen, K.; Goldman, A. S. "Assessment of the Electronic Factors Determining the Thermodynamics of ‘Oxidative Addition’ of C-H and N-H Bonds to Ir(I) Complexes"  J. Am. Chem. Soc.2016, 138, 149-163.
(DOI: 10.1021/jacs.5b09522)

183. Bolig, A. D.; Lyons, T. W.; DiSalvo, D. T.; Brookhart, M. "Intramolecular Hydrogen Transfer Reactions Catalyzed by Pentamethylcyclopentadienyl Rhodium and Cobalt Olefin Complexes: Mechanistic Studies", Polyhedron, 2016, 103, 51-57. 
(DOI:10.1016/j.poly.2015.07.076)
182. Liu, Y.; Mellmer, M. A.; Alonso, D. M.; Dumesic, J. A. " Effects of Water on the Copper-Catalyzed Conversion of Hydroxymethylfurfural in Tetrahydrofuran", ChemSusChem, 2015, 8, 3983-3986. 
(DOI:10.1002/cssc.201501122)
181. Chakraborty, S.; Piszel, P.; Brennessel, W. W.; Jones, W. D. "A Single Nickel Catalyst for the Acceptorless Dehydrogenation of Alcohols and Hydrogenation of Carbonyl Compounds", Organometallics, 2015, 34, 5203-5206.
(DOI:10.1021/acs.organomet.5b00824)
180. Chen, Y.; Choi, S.; Thompson, L. T. "Ethyl Formate Hydrogenolysis over Mo2C-Based Catalysts: Towards Methanol Synthesis from CO/CO2 Hydrogenation", Catal. Today2015, 259, 285-291.
(DOI:10.1016/j.cattod.2015.08.021)
179. Chakraborty, S.; Piszel, P. E.; Hayes, C. E.; Baker, R. T.; Jones, W. D. "Highly Selective Formation of n-Butanol from Ethanol through the Guerbet Process: A Tandem Catalytic Approach", J. Am. Chem. Soc.2015, 137, 14264-14267. 
(DOI:10.1021/jacs.5b10257
)
178. Wyvratt, B. M.; Gaudet, J. R.; Thompson, L. T. "Effects of Passivation on Synthesis, Structure and Composition of Molybdenum Carbide Supported Platinum Water-Gas Shift Catalysts", J. Catal., 2015, 330, 280-287.
(DOI:10.1016/j.jcat.2015.07.023)
177. Xu, R.; Chakraborty, S.; Yuan, H.; Jones, W. D. "Acceptorless, Reversible Dehydrogenation and Hydrogenation of N-heterocycles with a Cobalt Pincer Catalyst", ACS Catalysis, 2015, 5, 6350-6354.
(DOI:10.1021/acscatal.5b02002)
176. Lyons, T. W.; Bezier, D.; Brookhart, M. "Iridium Pincer-Catalyzed Dehydrogenation of Ethers Featuring Ethylene as the Hydrogen Acceptor", Organometallics201534, 4058-4062.
(DOI:10.1021/acs.organomet.5b00501)
175. Bellows, S. M.; Cundari, T. R.; Jones, W. D. "Methane Is the Best Substrate for C(sp3)–H Activation with Cp*(PMe3)Co(Me)(OTf): A Density Functional Theory Study",Organometallics, 2015, 34, 4032-4038.
(DOI: 10.1021/acs.organomet.5b00452)
174. Kumar, A.; Zhou, T.; Emge, T. J.; Zhuo, G.; Mironov, O.; Saxton, R. J.; Krogh-Jespersen, K.; Goldman, A. S. "Dehydrogenation of n-Alkanes by Solid-Phase Molecular Pincer-Iridium Catalysts. High Yields of α-Olefin Product", J. Am. Chem. Soc., 2015, 137, 9894-9911.
(DOI: 10.1021/jacs.5b05313)
173. Hanson, S. K.; Baker, R. T. "Knocking on Wood: Base Metal Complexes as Catalysts for Selective Oxidation of Lignin Models and Extracts", Acc. Chem. Res., 2015, 48, 2037-2048.
(DOI: 10.1021/acs.accounts.5b00104)
172. Denard, C. A.; Bartlett, M. J.; Wang, Y.; Lu, L.; Hartwig, J. F.; Zhao, H. "Development of a One- Pot Tandem Reaction Combining Ruthenium-catalyzed Alkene Metathesis and Enantioselective Enzymatic Oxidation to Produce Aryl Epoxides", ACS Catal., 2015, 5, 3817-3822.
(DOI: 10.1021/acscatal.5b00533)
171. Kovach, J.; Brennessel, W. W.; Jones, W. J. "Electrophilic C-H Activation of Benzene with a Shilov-inspired Rhodium(III) Diimine Complex", J. Organomet. Chem. 2015, 793, 192-199.
(DOI: 10.1016/j.jorganchem.2015.05.005)
170. Xiao, H.; Z. Bao, Z.; Zhao, H. “High Throughput Screening and Selection Methods for Directed Enzyme Evolution” Ind. Eng. Chem. Res., 2015, 54, 4011−4020.
(DOI: 10.1021/ie503060a)
169. Zhou, M.; Goldman, A. S., "Chlorination of (Phebox)Ir(mesityl)(OAc) by ThionylChloride", Molecules, 2015, 20, 10122-10130.
(DOI: 10.3390/molecules200610122)
168. Fujita, E.; Goldman, A. S. "Preface for Small-Molecule Activation: Carbon-Containing Fuels", Inorg. Chem., 2015, 54, 5040-5042.
(DOI: 10.1021/acs.inorgchem.5b00790)
167. Zhou, M.; Johnson, S. I.; Gao, Y.; Emge, T. J.; Nielsen, R. J.; Goddard, W. A., III; Goldman, A. S. "Activation and Oxidation of Mesitylene C–H Bonds by (Phebox)Iridium(III) Complexes", Organometallics, 2015, 34, 2879-2888.
(DOI: 10.1021/acs.organomet.5b00200)
166. Goldberg, J. M.; Wong, G. W.; Brastow, K. E.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. "The Importance of Steric Factors in Iridium Pincer Complexes", Organometallics, 2015, 34, 753-762.
(DOI: 10.1021/om501166w)
165. Chen, Y.; Choi, S.; Thompson, L. T. "Low-Temperature CO2 Hydrogenation to Liquid Products via a Heterogeneous Cascade Catalytic System", ACS Catal., 2015, 5, 1717-1725.
(DOI: 10.1021/cs501656x)
164. Cook, A. K.; Sanford, M. S. "Mechanism of the Palladium-Catalyzed Arene C-H Acetoxylation: A Comparison of Catalysts and Ligand Effects", J. Am. Chem. Soc., 2015, 137, 3109-3118.
(DOI: 10.1021/jacs.5b00238)
163. Lehman, M. C.; Pahls, D. R.; Meredith, J. M.; Sommer, R. D.; Heinekey, D. M.; Cundari, T. R.; Ison, E. A. "Oxyfunctionalization with Cp*IrIII(NHC)(Me)(Cl) with O2: Identification of a Rare Bimetallic IrIV µ-Oxo Intermediate", J. Am. Chem. Soc., 2015, 137, 3574-3584.
(DOI: 10.1021/ja512905t)
162. Rezayee, N. M.; Huff, C. A.; Sanford, M. S. "Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol", J. Am. Chem. Soc., 2015, 137, 1028-1031.
(DOI: 10.1021/ja511329m)
161. Denard, D. A.; Ren, H.; Zhao, H. "Improving and Repurposing Biocatalysts via Directed Evolution", Curr. Opin. Chem. Biol., 2015, 25, 55-64.
(DOI: 10.1016/j.cbpa.2014.12.036)
160. Frasco, D. A.; Sommer, R. D.; Ison, E. A. "ortho-C–H Activation of Thiobenzoic Acid: Synthesis, Characterization, and Reactivity of Iridium Thiobenzoate Complexes", Organometallics, 2015, 34, 275-279.
(DOI: 10.1021/om501115u)
159. Laviska, D. A.; Field, K. D.; Sparks, S. M.; Goldman, A. S. "The LEEDAR Program: Learning Enhanced through Experimental Design and Analysis with Rutgers", in Service Learning and Environmental Chemistry: Relevant Connections; Roberts-Kirchhoff, E. S.; Mio, M. J.; Benvenuto, M. A., Eds.; ACS Symposium Series 1177; American Chemical Society: Washington, DC, 2014, pp 209-228.
(DOI: 10.1021/bk-2014-1177.ch012)
158. Pahls, D. R.; Allen, K. E.; Goldberg, K. I.; Cundari, T. R. "Understanding the Effect of Ancillary Ligands on Concerted Metalation–Deprotonation by (dmPhebox)Ir(OAc)2(H2O) Complexes: A DFT Study", Organometallics, 201433, 6413-6419.
(DOI: 10.1021/om500752m)
157. Ou, W. C.; Cundari, T. R. "DFT Modeling of the Aldehyde-Water Shift Reaction with a Cationic Cp*Ir Catalyst", ACS Catal., 2015, 5, 225-232. 
(DOI: 10.1021/cs501222m)
156. Barrett, S. M.; Pitman, C. L.; Walden, A. G.; Miller, A. J. M. "Photoswitchable Hydride Transfer from Iridium to 1-Methylnicotinamide Rationalized by Thermochemical Cycles", J. Am. Chem. Soc., 2014, 136, 14718-14721.
(DOI: 10.1021/ja508762g)
155. Lehman, M. C.; Boyle, P. D.; Sommer, R. D.; Ison, E. A. "Oxyfunctionalization with Cp*IrIII(NHC)(Me)L Complexes", Organometallics, 2014, 33, 5081-5084.
(DOI: 10.1021/om5007352)
154. Bezier, D.; Brookhart, M. "Applications of PC(sp3)P Iridium Complexes in Transfer Dehydrogenation of Alkanes", ACS Catal., 2014, 4, 3411-3420.
(DOI: 10.1021/cs500892p)
153. Turlington, C. R.; Morris, J.; White, P. S.; Brennessel, W. W.; Jones, W. D.; Brookhart, M.; Templeton, J. L. "Exploring Oxidation of Half-Sandwich Rhodium Complexes: Oxygen Atom Insertion into the Rhodium–Carbon Bond of κ2-Coordinated 2-Phenylpyridine", Organometallics, 2014, 33, 4442-4448.
(DOI: 10.1021/om500660n)
152. Dobereiner, G. E.; Erdogan, G.; Larsen, C. R.; Grotjahn, D. B.; Schrock, R. R. "A One-Pot Tandem Olefin Isomerization/Metathesis-Coupling (ISOMET) Reaction", ACS Catal., 2014, 4, 3069-3076.
(DOI: 10.1021/cs500889x)
151. Brewster, T. P.; Ou, W. C.; Tran, J. C.; Goldberg, K. I.; Hanson, S. K.; Cundari, T. R.; Heinekey, D. M. " Iridium, Rhodium, and Ruthenium Catalysts for the "Aldehyde-Water Shift" Reaction", ACS Catal., 2014, 4, 3034-3038.
(DOI: 10.1021/cs500843a)
150. Pitman, C. L.; Miller, A. J. M. "Molecular Photoelectrocatalysts for Visible Light-Driven Hydrogen Evolution from Neutral Water", ACS Catal., 2014, 4, 2727-2733.
(DOI: 10.1021/cs500441f)
149. Huang, H.; Denard, C. A.; Alamillo, R.; Crisci, A. J.; Miao, Y.; Dumesic, J. A.; Scott, S. L.; Zhao, H. "Tandem Catalytic Conversion of Glucose to 5-Hydroxymethylfurfural with an Immobilized Enzyme and a Solid Acid", ACS Catal., 2014, 4, 2165-2168.
(DOI: 10.1021/cs500591f)
148. Lotz, M. D.; Remy, M. S.; Lao, D. B.; Afiafard, A.; Yater, B. F.; Canty, A. J.; Mayer, J. M.; Sanford, M. S. "Formation of Ethane from Mono-Methyl Palladium(II) Complexes",  J. Am. Chem. Soc., 2014, 136, 8237-8242.
(DOI: 10.1021/ja412338k)
147. Lanci, M.P.; McKeown, B.A.; Lao, D.B.; Spettel, K.E.; Mayer, J.M. "One Electron Oxidation of (L2)PdII(CH3)2 Complexes: Ligand Effects on Production of Ethane vs. Pd-C Bond Homolysis", Polyhedron, 2014, 84,44 -50.          
(DOI: 10.1016/j.poly.2014.06.008)
146. Barnett, S. M.; Waidmann, C. R.; Scheuermann, M. L.; Nesvet, J. C.; Goldberg, K. I.; Mayer, J. M.  Chapter 11 "Developing Molecular Copper Complexes for Water Oxidation", in Molecular Water Oxidation Catalysts. Llobet, A., Ed. Wiley-Interscience: New York; June 2014.
http://www.wiley.com/WileyCDA/WileyTitle/productCd-1118413377.html
145. Jiao, Y.; Brennessel, W. W.; Jones, W. D. "Synthesis and energetics of Tp′Rh[P(OMe)3](R)H: A systematic investigation of ligand effects on C-H activation at rhodium", Chem. Sci., 2014, 5, 804-812.
(DOI: 10.1039/c3sc52748d)
144. Gladysz, J. A.; Bedford, R. B.; Fujita, M.; Gabbai, F. P.; Goldberg, K. I.; Holland, P. L.; Kiplinger, J. L.; Krische, M. J.; Louie, J.; Lu, C. C.; Norton, J. R.; Petrukhina, M. A.; Ren, T.; Stahl, S. S.; Tilley, T. D.; Webster, C. E.; White, M. C.; Whiteker, G. T. "Organometallics Roundtable 2013-2014", Organometallics, 2014, 33, 1505-1527.
(DOI: 10.1021/om500253z)
143. Barta, K.; Ford, P. C. "Catalytic Conversation of Nonfood Woody Biomass Solids to Organic Liquids", Acc. Chem. Res., 2014, 136, 6672-6683.
(DOI: 10.1021/ar4002894)
142. Cheng, C.; Kim, B. G.; Guironnet, D.; Brookhart, M.; Guan, C.; Wang, D. Y.; Krogh-Jespersen, K.; Goldman, A. S. "Synthesis and Characterization of Carbazolide-based Iridium PNP Pincer Complexes. Mechanistic and Computational Investigation of Alkene Hydrogenation: Evidence for an IrIII/Ir(V)/IrIII Catalytic Cycle", J. Am. Chem. Soc., 2014, 136, 6672-6683.
(DOI: 10.1021/ja501572g)
141. Eriksen, D.; Lian, J.; Zhao, H. "Protein Design for Pathway Engineering", J. Struct. Biol., 2014, 185, 234–242.
(DOI: 10.1016/j.jsb.2013.03.011)
 
140. Chen, Y.; Thompson, L. T. "Liquid phase CO2 hydrogenation to methanol over Mo2C-based catalysts", Prepr. Symp. - Am. Chem. Soc., Div. Fuel Chem., 2014, 59, 395-396.
139. Gruhn, N. E.; Brookhart, M.; Goldberg, K. I. "Virtual Issue on Research in the Center for Enabling New Technologies Through Catalysis (CENTC)", ACS Catal., 2014, 4, 1318-1319.
(DOI: 10.1021/cs500312z)
138. Allen, K. E.; Heinekey, D. M; Goldman, A. S.; Goldberg, K. I. "Regeneration of an IrIII Complex Active for Alkane Dehydrogenation Using Molecular Oxygen", Organometallics, 2014, 33, 1337-1340.  
(DOI: 10.1021/om401241e)
 
137. Miller, A. J. M.; Kaminsky, W.; Goldberg, K. I. "Arene Activation at Iridium Facilitates C–O Bond Cleavage of Aryl Ethers", Organometallics, 2014, 33, 1245-1252.
(DOI: 10.1021/om5000166)
136. Denard, C. A.; Huang, H.; Bartlett, M. J.; Lu, L.; Tan, Y.; Zhao, H.; Hartwig, J. F. "Cooperative Tandem Catalysis by an Organometallic Complex and a Metalloenzyme", Angew. Chem. Int. Ed. Eng., 2014, 53, 465-469.
(DOI: 10.1002/anie.201305778)
135. O'Neill, B. J.; Jackson, D. H. K.; Crisci, A. J.; Farberow, C. A.; Shi, F.; Alba-Rubio, A. C.; Lu, J.; Dietrich, P. J.; Gu, X.; Marshall, C. L.; Stair, P. C.; Elam, J. W.; Miller, J. T.; Ribeiro, F. H.; Voyles, P. M.; Greeley, J.; Mavrikakis, M.; Scott, S. L.; Kuech, T. F.; Dumesic, J. A. "Stabilization of Copper Catalysts for Liquid-Phase Reactions by Atomic Layer Deposition", Angew. Chem. Int. Ed. Eng., 2013, 52, 13808-13812.
(DOI: 10.1002/anie.201308245)
134. Sedai, B.; Diaz-Urrutia, C.; Baker, R. T.; Wu, R.; Silks, L. A.; Hanson, S. K. "Aerobic Oxidation of ß-1 Lignin Model Compounds with Copper and Oxovanadium Catalysts", ACS Catal., 2013, 3, 3112-3122.
(DOI: 10.1021/cs400636k)
133. Cook, A. K.; Emmert, M. H.; Sanford, M. S. "Steric Control of Site Selectivity in the Pd-Catalyzed C–H Acetoxylation of Simple Arenes", Org. Lett., 2013, 15, 5428-5431.
(DOI: 10.1021/ol4024248)
132. Jackson, D. H. K.; Wang, D.; Gallo, J. M. R.; Crisci, A. J.; Scott, S. L.; Dumesic, J. A.; Kuech, T. F. "Amine Catalyzed Atomic Layer Deposition of (3-Mercaptopropyl)trimethoxysilane for the Production of Heterogeneous Sulfonic Acid Catalysts", Chem. Mater., 2013, 25, 3844-3851.
(DOI: 10.1021/cm401607g)

131. Brewster, T. P.; Miller, A. J. M.; Heinekey, D. M.; Goldberg, K. I. "Hydrogenation of Carboxylic Acids Catalyzed by Half-Sandwich Complexes of Iridium and Rhodium", J. Am. Chem. Soc., 2013, 135, 16022-16025.
(DOI: 10.1021/ja408149n

130. Huff, C. A.; Sanford, M. S. "Catalysis CO2 Hydrogenation to Formate by a Ruthenium Pincer Complex", ACS Catal., 2013, 3, 2412-2416.
(DOI: 10.1021/cs400609u)
129. Dobereiner, G. E.; Yuan, J.; Schrock, R. R.; Goldman, A. S.; Hackenberg, J. D. "Catalytic Synthesis of n-Alkyl Arenes through Alkyl Group Cross Metathesis", J. Am. Chem. Soc., 2013, 135, 12572-12575.
(DOI: 10.1021/ja4066392)
128. Lao, D. B.; Owens, A. C. E.; Heinekey, D. M.; Goldberg, K. I. "Partial Deoxygenation of Glycerol Catalyzed by Iridium Pincer Complexes", ACS Catal., 2013, 3, 2391-2396.
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37. Li, L.; Jiao, Y.; Brennessel, W. W.; Jones, W. D. "Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M-C (M = Ir, Rh) Bonds of Cylometallated Complexes", Organometallics, 2010, 29, 4593-4606.
(DOI:10.1021/om100796q)
36. Nair, N. U.; Denard, C. A.; Zhao, H., "Engineering of Enzymes for Selective Catalysis", Curr. Org. Chem., 2010, 14, 1870-1882.
(DOI:10.2174/138527210792927537)
35. Warren, J. J.; Tronic, T. A.; Mayer, J. M., "Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications", Chem. Rev., 2010, 110, 6961-7001.
(DOI:10.1021/cr100085k)
34. Nair, N. U.; Zhao, H., "Selective reduction of xylose to xylitol from a mixture of hemicellulosic sugars", Metab. Eng , 2010, 12, 462-468.
(DOI:10.1016/j.ymben.2010.04.005)
33. Barta, K.; Matson, T. D.; Fettig, M. L.; Scott, S. L.; Iretskii, A. V.; Ford, P. C., "Catalytic disassembly of an organosolv lignin via hydrogen transfer from supercritical methanol", Green Chemistry , 2010, 12, 1640-1647. (DOI:10.1039/C0GC00181C)
32. Emmert, M. H.; Gary, J. B.; Villalobos, J. M.; Sanford, M. S., "Platinum and Palladium Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation", Angew. Chem. Int. Ed. Eng., 2010, 49, 5884-5886.
(DOI:10.1002/anie.201002351)
31. Feng, Y.; Jiang, B.; Boyle, P. A.; Ison, E. A., "Effect of Ancillary Ligands and Solvents on H/D Exchange Reactions Catalyzed by Cp*Ir Complexes", Organometallics, 2010, 29, 2857.
(DOI: 10.1021/om100018x)
30. Crisci, A. J.; Tucker, M. H.; Dumesic, J. A.; Scott, S. L., "Bifunctional Solid Catalysts for the Selective Conversion of Fructose to 5-Hydroxymethylfurfural", Topics in Catalysis, 2010, 53, 1185-1192.
(DOI:10.1007/s11244-010-9560-2)
29. Hanson, S. K.; Baker, R. T.; Gordon, J. C.; Scott, B. L.; Thorn, D. L., "Aerobic Oxidation of Lignin Models Using a Base Metal Vanadium Catalyst", Inorg. Chem., 2010, 49, 5611-5618.
(DOI:10.1021/ic100528n)
28. Punji, B.; Emge, T. J.; Goldman, A. S., "A Highly Stable Adamantyl-Substituted Pincer-Ligated Iridium Catalyst for Alkane Dehydrogenation", Organometallics, 2010, 29, 2702-2709.
(DOI:10.1021/om100145q)
27. Huang, Z.; White, P. S.; Brookhart, M., "Ligand Exchanges and Selective Catalytic Hydrogenation in Molecular Single Crystals", Nature, 2010, 465, 598-601.
(DOI:10.1038/nature09085)
26. Findlater, M.; Bernskoetter, W. H.; Brookhart, M., "Proton-Catalyzed Hydrogenation of a d8 IrI Complex Yields a trans IrIII Dihydride", J. Am. Chem. Soc., 2010, 132, 4534-4535.
(DOI:10.1021/ja100168w)
25. Remy, M. S.; Cundari, T. R.; Sanford, M. S., "Computational and Experimental Studies of Methyl Group Exchange between Palladium(II) Centers", Organometallics, 2010, 29, 1522-1525.
(DOI: 10.1021/om901039u)
24. Tan, Y.; Hartwig, J. F., "Palladium-Catalyzed Amination of Aromatic C-H Bonds with Oxime Esters", J. Am. Chem. Soc., 2010, 132, 3676-3677.
(DOI:10.1021/ja100676r)
23. Ke, Z.; Cundari, T.R., "Palladium-Catalyzed C-H Activation/C-N Bond Formation Reactions: DFT Study of Reaction Mechanisms and Reactive Intermediates", Organometallics, 2010, 29, 821-834.
(DOI:10.1021/om900895t)
22. Huang, Z.; Rolfe, E.; Carson, E. C.; Brookhart, M.; Goldman, A. S.; El-Khalafy, S. H.; MacArthur, A. H. R. , "Efficient Heterogeneous Dual Catalyst Systems for Alkane Metathesis", Adv. Synth. Catal., 2010, 352, 125-135
(DOI: 10.1002/adsc.200900539)
21. Marquard, S. L.; Rosenfeld, D. C.; Hartwig, J. F., "C(sp3)-N Bond-Forming Reductive Elimination of Amines: Reactions of Bisphosphine-Ligated Benzylpalladium(II) Diarylamido Complexes", Angew. Chem. Int. Ed. Eng., 2010, 49, 793-796.
(DOI:10.1002/anie.200904032)
20. Villalobos, J. M.; Hickman, A. J.; Sanford, M. S., "Platinum(II) Complexes Containing Quaternized Nitrogen Ligands: Synthesis, Stability, and Evaluation as Catalysts for Methane and Benzene H/D Exchange", Organometallics, 2010, 29, 257-262.
(DOI:10.1021/om900889k)
19. Hickman, A.; Villalobos, J. A.; Sanford, M. S., "A Quantitative Method to Assay Platinum Catalysts for Benzene H/D Exchange", Organometallics, 2009, 28, 5316-5322.
(DOI:10.1021/om900495n)
18. Lanci, M. P.; Remy, M. S.; Kaminsky, W.; Mayer, J. M.; Sanford, M. S., "Oxidatively Induced Reductive Elimination from (tBu2bpy)Pd(Me)2: Palladium(IV) Intermediates in a One Electron Oxidation Reaction", J. Am. Chem. Soc., 2009, 131, 15618-15620.
(DOI:10.1021/ja905816q)
17. Wesley H. Bernskoetter, Cynthia K. Schauer, Karen I. Goldberg, and Maurice Brookhart, "Characterization of a Rhodium(I) σ-Methane Complex in Solution", Science, 2009, 326, 553-556.
(DOI:10.1126/science.1177485)
16. Kundu, S.; Choliy, Y.; Zhuo, G.; Ahuja, R.; Emge, T. J.; Warmuth, R.; Brookhart, M.; Krogh-Jespersen, K.; Goldman, A. S. "Rational Design and Synthesis of Highly Active Pincer-Iridium Catalysts for Alkane Dehydrogenation", Organometallics, 2009, 28, 5432-5444.
(DOI:10.1021/om900568f)
15. Bernskoetter, W. H.; Hanson, S. K.; Buzak, S. K.; Davis, Z.; White, P. S.; Swartz, R.; Goldberg, K. I.; Brookhart, M. "Investigations of Iridium Mediated Reversible C-H Bond Cleavage: Characterization of a 16-Electron Iridium(III) Methyl Hydride Complex", J. Am. Chem. Soc., 2009, 28, 3546-3551.
(DOI:10.1021/ja901706b)
14. Meredith, J. M.; Goldberg, K. I.; Kaminsky, W.; Heinekey, D. M. "Dinuclear Iridium Complexes Containing Cp* and Carbonyl Ligands: Synthesis, Structure and Reactivity" Organometallics, 2009, 28, 3546-3551.
(DOI:10.1021/om900186j)
13. Goldman, A. S.; Brookhart, M.; Huang, Z.; Krogh-Jespersen, K.; Kundu, S.; Scott, S. L. "Transition-metal-based catalytic systems for the dehydrogenation and metathesis of alkanes. Solution-phase and solid-supported iridium-based pincer catalysts." Prepr. Symp. - Am. Chem. Soc., Div. Fuel Chem., 2009, 54, 213-215.
12. Ter Horst, M.; Urbin, S.; Burton, R.; McMillan, C. "Using proton nuclear magnetic resonance as a rapid response research tool for methyl ester characterization of biodiesel", Lipid Technology, 2009, 21, 39-41.
(DOI:10.1002/lite.200900004)
11. Look, J. L.; Wick, D. D.; Mayer, J. M.; Goldberg, K. I. "Autoxidation of Platinum(IV) Hydrocarbyl Hydride Complexes to Form Platinum(IV) Hydrocarbyl Hydroperoxide Complexes", Inorg. Chem., 2009, 48, 1356-1369.
(DOI: 10.1021/ic801216r)
10. Huang, Z.; Brookhart, M.; Goldman, A. S.; Kundu, S.; Ray, A.; Scott, S. L.; Vicente, B. C. "Highly active and recyclable heterogeneous iridium pincer catalysts for transfer dehydrogenation of alkanes" Adv. Synth. Catal., 2009, 351, 188-206.
(DOI:10.1002/adsc.200800615)
9. Macala, G. S.; Matson, T. D.; Johnson, C. L.; Lewis, R.; Iretskii, A. V.; Ford, P. C. "Hydrogen Transfer from Super-critical Methanol over a Solid Base Catalysts. A Model for Lignin Depolymerization" ChemSusChem, 2009, 2, 215-217.
(DOI:10.1002/cssc.200900033)
8. Hanson, S. K.; Baker, R. T.; Gordon, J. C.; Scott, B. L.; Sutton, A. D.; Thorn, D. L. "Aerobic Oxidation of Pinacol by Vanadium(V) Dipicolinate Complexes: Evidence for Reduction to Vanadium(III)" J. Am. Chem. Soc., 2009, 131 (2), 428-429.
(DOI:10.1021/ja807522n)
7. Bailey, B. C.; Schrock, R. R.; Kundu, S.; Goldman, A. S.; Huang, Z.; Brookhart, M. "Evaluation of Molybdenum and Tungsten Metathesis Catalysts for Homogeneous Tandem Alkane Metathesis", Organometallics, 2009, 28(1), 355-360.
(DOI: 10.1021/om800877q)
6. Macala, G. S.; Robertson, A. W.; Johnson, C. L.; Day, Z. B.; Lewis, R. S.; White, M. G.; Iretskii, A. V.; Ford, P. C. "Transesterification Catalysts from Iron Doped Hydrotalcite-like Precursors: Solid Bases for Biodiesel Production" Catalysis Letters, 2008, 122(3-4), 205-209.
(DOI:10.1007/s10562-008-9480-y)
5. Nair, N. U.; Zhao, H. "Evolution in Reverse: Engineering a D-Xylose-specific Xylose Reductase" ChemBioChem, 2008, 9, 1213-1215.
(DOI: 10.1002/cbic.200700765)
4. Williams, D. B.; Kaminsky, W.; Mayer, J. M.; Goldberg, K. I., "Reactions of Iridium Hydride Pincer Complexes with Dioxygen: New Peroxo Complexes and Reversible O2 Binding" ChemComm., 2008, 35, 4195-4197.
(DOI: 10.1039/b802739k)
3. Foley, N. A.; Ke, Z.; Gunnoe, T. B.; Cundari, T. R.; Petersen, J. L. "Aromatic C-H Activation and Catalytic Hydrophenylation of Ethylene by TpRu{P(OCH2)3CEt}(NCMe)Ph" Organometallics, 2008, 27(13), 3007-3017.
(DOI:10.1021/om800275b)
2. Hanson, S. K.; Heinekey, D. M.; Goldberg, K. I. "C-H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H−D Exchange between Arenes and Water" Organometallics, 2008, 27(7), 1454-1463.
(DOI:10.1021/om7012259)
1. Ahuja, R.; Kundu, S.; Goldman, A. S.; Brookhart, M.; Vicente, B. C.; Scott, S. L. "Catalytic Ring Expansion, Contraction, and Metathesis-Polymerization of Cycloalkanes" ChemComm., 2008, 253-255.
(DOI: 10.1039/b712197k)

CATSB (Phase I) Publications:

1. Kloek, Susan M.; Heinekey, D. Michael; Goldberg, Karen I.; "C-H bond activation by rhodium(I) hydroxide and phenoxide complexes" Angewandte Chemie, International Edition, 2007, 46(25), 4736-4738
(DOI: 10.1002/anie.200700270)
2. Kloek, Susan M.; Goldberg, Karen I. "Competitive C-H Bond Activation and β-Hydride Elimination at Platinum(II)" J. Am. Chem. Soc., 2007, 129 (12), 3460-3461
(DOI: 10.1021/ja0669629)
3. X. Zhang; T. J. Emge; A. S. Goldman, "Selective Cleavage of the C-C Bond of Aminoethyl Groups, via a Multistep Pathway, by a Pincer Iridium Complex", J. Am. Chem. Soc., 2005, 127, 8250
(DOI: 10.1021/ja051300p)
4. Alan S. Goldman; Amy H. Roy; Zheng Huang; Ritu Ahuja; William Schinski; Maurice Brookhart, "Catalytic Alkane Metathesis by Tandem Alkane-Dehydrogenation-Olefin-Metathesis", Science, 2006, 312, 257
(DOI: 10.1126/science.1123787)
5. Susan M. Kloek; D. Michael Heinekey; Karen I. Goldberg, "Stereoselective Decarbonylation of Methanol to Form a Stable Iridium(III) Trans-Dihydride Complex", Organometallics, 2006, 25, 3007
(DOI: 10.1021/om051098z)
6. Devon C. Rosenfeld; Shashank Shekhar; Akihiro Takemiya; Masaru Utsunomiya; John F. Hartwig*, "Hydroamination and Hydroalkoxylation Catalyzed by Triflic Acid. Parallels to Reactions Initiated with Metal-Triflates", Org. Lett., 2006, 8 (19), 4179-4182
(DOI: 10.1021/ol061174+)
7. Inigo Göttker-Schnetmann; D. M. Heinekey; Maurice Brookhart, "Temperature and Solvent Dependent Binding of Dihydrogen in Iridium Pincer Complexes."  J. Am. Chem. Soc., 2006, 128, 17115-17119
(DOI: 10.1021/ja065854j)