CENTC Publications

Publications

Publications

This publication list was last updated on July 24, 2018. Visit the CENTC Google Scholar page for the most up to date list of publications and citations.

241. Peacock, D. M.; Jiang, Q.; Hanley, P. S.; Cundari, T. R.; Hartwig, J. F. “Reductive Elimination from Phosphine-Ligated Alkylpalladium(II) Amido Complexes To Form sp3 Carbon–Nitrogen Bonds”, J. Am. Chem. Soc., 2018, 140, 4893-4904.
(DOI: 10.1021/jacs.8b00928)

240. Wilklow-Marnell, M.; Brennessel, W. W.; Jones, W. D. “Reactivity of iPrPCPIrH4with para-benzoquinones” Polyhedron, 2018, 143, 209-214.
(DOI: 10.1016/j.poly.2017.10.026)

239. Bruch, Q. J.; Lindley, B. M.; Askevold, B.; Schneider, S.; Miller, A. J. M. “A Ruthenium Hydrido Dinitrogen Core Conserved across Multielectron/Multiproton Changes to the Pincer Ligand Backbone”, Inorg. Chem.,2018, 57, 1964-1975.
(DOI: 10.1021/acs.inorgchem.7b02889)

238. Yuan, H.; Brennessel, W. W.; Jones, W. D. “Effect of Carboxylate Ligands on Alkane Dehydrogenation with (dmPhebox)Ir Complexes”, ACS Catal., 2018, 8, 2236-2329.
(DOI: 10.1021/acscatal.7b04057)

237. Gao, Y.; Emge, T. J.; Krogh-Jespersen, K.; Goldman, A. S. “Selective Dehydrogenative Coupling of Ethylene to Butadiene via an Iridacyclopentane Complex”, J. Am. Chem. Soc., 2018, 140, 2260-2264.
(DOI: 10.1021/jacs.7b11689)

236. Lekich, T. T.; Askelson, P. G.; Burdick, R. K.; Heinekey, D. M. “An Improved Synthesis of Me4PCP and DMPE”, Organometallics, 2018, 37, 211-213.
(DOI: 10.1021/acs.organomet.7b00780)

235. Kulkarni, N. V.; Brennessel, W. W.; Jones, W. D. “Catalytic Upgrading of Ethanol to n-Butanol via Manganese-Mediated Guerbet Reaction”, ACS Catal., 2018, 8, 997-1002.
(DOI: 10.1021/acscatal.7b03653)

234. Bukhryakov, K. V.; VenkatRamani, S.; Tsay, C.; Hoveyda, A.; Schrock, R. R. “Syntheses of Molybdenum Adamantylimido and t-Butylimido Alkylidene Chloride Complexes Using HCl and Diphenylmethylphosphine”, Organometallics, 2017, 36, 4208-4214.
(DOI: 10.1021/acs.organomet.7b00647)

233. Kumar, A.; Bhatti, T.; Goldman, A. “Dehydrogenation of Alkanes and Aliphatic Groups by Pincer-Ligated Metal Complexes”, Chem. Rev., 2017, 117, 12357-12384.
(DOI: 10.1021/acs.chemrev.7b00247)

232. Connor, G. P.; Lease, N.; Casuras, A.; Goldman, A. S.; Holland, P. L.; Mayer, J. M. “Protonation and Electrochemical Reduction of Rhodium- and Iridium-dinitrogen Complexes in Organic Solution”, Dalton Trans.2017, 46, 14325-14330.
(DOI: 10.1039/C7DT03476H)

231. Sues, P. E.; Bukhryakov, K. V.; Schrock, R. R. “Evaluation of Several Molybdenum and Ruthenium Catalysts for the Metathesis Homocoupling of 3-Methyl-1-Butene”, Helv. Chim. Acta, 2017, 100, e1700181.
(DOI: 10.1002/hlca.201700181)

230. Wilklow-Marnell, M.; Brennessel, W. W.; Jones, W. D. “C(sp2)-F Oxidative Addition of Fluorinated Aryl Ketones by iPrPCPIr”, Organometallics, 2017, 36, 3125-3134.
(DOI: 10.1021/acs.organomet.7b00466)

229. Goldberg, J. M.; Goldberg, K. I.; Heinekey, D. M.; Burgess, S. A.; Lao, D. B.; Linehan, J. C. “Detection of an Iridium–Dihydrogen Complex: A Proposed Intermediate in Ionic Hydrogenation”, J. Am. Chem. Soc.,2017, 139, 12638-12646.
(DOI: 10.1021/jacs.7b06480)

228. Wilklow-Marnell, M.; Brennessel, W. W.; Jones, W. D. “Unexpected Solvent Effects in the Isomerization of iPrPCPIr(η2-PhC≡CPh) to a 1-Iridaindene”, Isr. J. Chem., 2017, 57, 968-974.
(DOI: 10.1002/ijch.201700013)

227. Wilklow-Marnell, M.; Jones, W. D. “Catalytic Oxidation of Carbon Monoxide by α-Alumina Supported 3 nm Cerium Dioxide Nanoparticles”, Mol. Catal., 2017, 439, 9-14.
(DOI: 10.1016/j.mcat.2017.06.015)

226. Wilklow-Marnell, M.; Li, B.; Zhou, T.; Krogh-Jespersen, K.; Brennessel, W. W.; Emge, T. J.; Goldman, A. S.; Jones, W. D. “Catalytic Dehydrogenative C-C Coupling by a Pincer-Ligated Iridium Complex”, J. Am. Chem. Soc., 2017, 139, 8977-8989.
(DOI: 10.1021/jacs.7b03433)

225. Stevens, T. E.; Smoll, K. A.; Goldberg, K. I. “Direct Formation of Carbon(sp3)–Heteroatom Bonds from RhIII To Produce Methyl Iodide, Thioethers, and Alkylamines”, J. Am. Chem. Soc., 2017, 139, 7725–7728.
(DOI: 10.1021/jacs.7b04169)

224. Goldberg, J. M.; Berman, J. L.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. “Oxidative addition of iodine to (tBu)4(POCOP)Ir(CO) complexes”, J. Organomet. Chem., 2017, 854, 171-176.
(DOI: 10.1016/j.jorganchem.2017.04.036)

223. Qi, L.; Alamillo, R.; Elliott, W. A.; Andersen, A.; Hoyt, D. W.; Walter, E. D.; Han, K. S.; Washton, N. M.; Rioux, R. M.; Dumesic, J. A.; Scott, S. L. “Operando Solid-State NMR Observation of Solvent-Mediated Adsorption-Reaction of Carbohydrates in Zeolites”, ACS Catal.,2017, 7, 3489-3500.
(DOI: 10.1021/acscatal.7b01045)

222. Bellows, S. M.; Chakraborty, S.; Gary, J. B.; Jones, W. D.; Cundari, T. R. “An Uncanny Dehydrogenation Mechanism: Polar Bond Control over Stepwise or Concerted Transition States”, Inorg. Chem., 2017, 56, 5519-5524.
(DOI: 10.1021/acs.inorgchem.6b01800)

221. Gao, Y.; Guan, C.; Zhou, M.; Kumar, A.; Emge, T. J.; Wright, A. M.; Goldberg, K. I.; Krogh-Jespersen, K.; Goldman, A. S. “β-Hydride Elimination and C-H Activation by an Iridium Acetate Complex, Catalyzed by Lewis Acids. Alkane Dehydrogenation Co-Catalyzed by Lewis Acids and (Phebox)Ir”, J. Am. Chem. Soc., 2017,139, 6338–6350.
(DOI: 10.1021/jacs.6b12995)

220. Lindley, B. M.; Bruch, Q. J.; White, P. S.; Hasanayn, F.; Miller, A. J. M. “Ammonia Synthesis from a Pincer Ruthenium Nitride via Metal–Ligand Cooperative Proton-Coupled Electron Transfer”, J. Am. Chem. Soc.,2017, 139, 5305-5308.
(DOI: 10.1021/jacs.7b01323)

219. Goldberg, K. I.; Goldman, A. S. “Large-Scale Selective Functionalization of Alkanes”, Acc. Chem. Res., 2017, 50, 620-626.
(DOI: 10.1021/acs.accounts.6b00621)

218. Wang, Y.; Bartlett, M. J.; Denard, C. A.; Hartwig, J. F.; Zhao, H. “Combining Rh-Catalyzed Diazocoupling and Enzymatic Reduction To Efficiently Synthesize Enantioenriched 2-Substituted Succinate Derivatives”, ACS Catal., 2017, 7, 2548-2552.
(DOI: 10.1021/acscatal.7b00254)

217. Arnold, P. L.; Stevens, C. J.; Bell, N. L.; Lord, R. M.; Goldberg, J. M.; Nichol, G. S.; Love, J. B. “Multi-electron reduction of sulfur and carbon disulfide using binuclear uranium(III) borohydride complexes”, Chem. Sci., 2017, 8, 3609–3617.
(DOI: 10.1039/C7SC00382J)

216. Fazlur Rahman, A. K.; Wilklow-Marnell, M.; Brennessel, W. W.; Jones, W. D. “Crystal Structure of Chloridobis[(1,2,5,6-η)-cycloocta-1,5-diene]iridium(I)”, Acta Cryst. E, 2017, 73, 273-277.
(DOI: 10.1107/S2056989017000809)

215. Wang, Y.; Zhao, H. “Tandem Reactions Combining Biocatalysts and Chemical Catalysts for Asymmetric Synthesis”, Catalysts, 2016, 6, 194-214.
(DOI: /10.3390/catal6120194)

214. Wiedner, E. S.; Chambers, M. B.; Pitman, C. L.; Bullock, R. M.; Miller, A. J. M.; Appel, A. M. "Thermodynamic Hydricity of Transition Metal Hydrides.” Chem. Rev., 2016, 116, 8655-8692.
(DOI: 10.1021/acs.chemrev.6b00168)

213. Brereton, K. R.; Bellows, S. M.; Fallah, H.; Lopez, A. A.; Adams, R. M.; Miller, A. J. M.; Jones, W. D.; Cundari, T. R. “Aqueous Hydricity from Calculations of Reduction Potential and Acidity in Water”, J. Phys. Chem. B., 2016, 120, 12911-12919.
(DOI: 10.1021/acs.jpcb.6b09864)

212. Kumar, A.; Hackenberg, J. D.; Zhou, G. Steffens, A. M.; Mironov, O.; Saxton, R. J.; Goldman, A. S. “High Yields of Piperylene in the Transfer Dehydrogenation of Pentane Catalyzed by Pincer-ligated Iridium Complexes”, J. Mol. Catal. A, 2017, 426, 368-375.
(DOI: 10.1016/j.molcata.2016.10.019)

211. Brereton, K. R.; Pitman, C. L.; Cundari, T. R.; Miller, A. J. M. “Solvent-Dependent Thermochemistry of an Iridium/Ruthenium H2 Evolution Catalyst”, Inorg. Chem., 2016, 55, 12042-12051.
(DOI: acs.inorgchem.6b02223)

210. Sues, P. E.; John, J. M.; Bukhryakov, K. V.; Schrock, R. R.; Muller, P. “Molybdenum and Tungsten Alkylidene Complexes That Contain a 2-Pyridyl-Substituted Phenoxide Ligand”, Organometallics, 2016, 35, 3587-3593.
(DOI: 10.1021/acs.organomet.6b00644)

209. Peacock, D. M.; Roos, C. B.; Hartwig, J. F. “Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile”, ACS Cent. Sci., 2016, 2, 647-652.
(DOI: 10.1021/acscentsci.6b00187)

208. Goldberg, J. M.; Cherry, S. D. T.; Guard, L. M.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. “Hydrogen Addition to (pincer)IrI(CO) Complexes: The Importance of Steric and Electronic Factors”, Organometallics, 2016, 35, 3546-3556.
(DOI: 10.1021/acs.organomet.6b00598)

207. Connor, G. P.; Holland, P. L. “Coordination Chemistry Insights into the Role of Alkali Metal Promoters in Dinitrogen Reduction”, Catalysis Today, 2016, in press.
(DOI: 10.1016/j.cattod.2016.08.014)

206. Brewster, T. P., Tran, J. C., Heinekey, D. M., Goldberg, K. I. "High Catalytic Efficiency Combined with High Selectivity for the Aldehyde-Water Shift using ( para -cymene)Ruthenium Precatalysts", ACS Catal., 2016, 6, 6302-6305.
(DOI: 10.1021/acscatal.6b02130)

205. Rezayee, N. M.; Samblanet, D. C.; Sanford, M. S. “Iron-Catalyzed Hydrogenation of Amides to Alcohols and Amines”, ACS Catal., 2016, 6, 6377-6383.
(DOI: 10.1021/acscatal.6b01454)

204. Lindley, B. M.; Appel, A. M.; Krogh-Jespersen, K.; Mayer, M. J.; Miller, A. J. M. “Evaluating the Thermodynamics of Electrocatalytic N2 Reduction in Acetonitrile”, ACS Energy Lett., 2016, 1, 698-704.
(DOI: 10.1021/acsenergylett.6b00319)

203. Wyvratt, B. M.; Gaudet, J. R.; Pardue, D. B.; Marton, A.; Rudic, S.; Mader, E. A.; Cundari, T. R.; Mayer, J. M.; Thompson, L. T. “Reactivity of Hydrogen On and In Nanostructured Molybdenum Nitride: Crotonaldehyde Hydrogenation”, ACS Catal., 2016, 6, 5797-5806.
(DOI: 10.1021/acscatal.6b00936)

202. Lotz, M. D.; Camasso, N. M.; Canty, A. J.; Sanford, M. S. “Role of Silver Salts in Palladium-Catalyzed Arene and Heteroarene C–H Functionalization Reactions”, Organometallics, 2016, in press.
(DOI: 10.1021/acs.organomet.6b00437)

201. Munjanja, L.; Torres-Lopez, C.; Brennessel, W. W.; Jones, W. D. “C–CN Bond Cleavage Using Palladium Supported by a Dippe Ligand”, Organometallics, 2016, 35, 2010-2013.
(DOI: 10.1021/acs.organomet.6b00304)

200. Pitman, C. L.; Finster, O. N. L.; Miller, A. J. M. "Cyclopentadiene-Mediated Hydride Transfer from Rhodium Complexes.” Chem. Commun.,2016, 52, 9105-9108.
(DOI: 10.1039/C6CC00575F)

199. Bezier, D., Brookhart, M.,“Transfer Dehydrogenations of Alkanes and Related Reactions using Iridium Pincer Complexes“ in C-H Bond Activation and Catalytic Functionalization II, Topics in Organometallic Chemistry, Eds. Dixneuf, P.H., Doucet, H., Springer, 2016.
(DOI: 10.1007/3418_2015_132)

198. Kumar, A.; Goldman, A. S. "Recent Advances in Alkane Dehydrogenation Catalyzed by Pincer Complexes" In Top. Organomet. Chem., van Koten, G., Gossage, R. A., Eds.; Springer International Publishing, 2016; Vol. 54, p 307-334. 
(DOI: 10.1007/3418_2015_113)

197. Yao, W.; Jia, X.; Leng, X.; Goldman, A. S.; Brookhart, M.; Huang, Z. "Catalytic Alkane Transfer-Dehydrogenation by PSCOP Iridium Pincer Complexes", Polyhedron, 2016, 116, 12-19.
(DOI: 10.1016/j.poly.2016.02.044)

196. Wilklow-Marnell, M.; Brennessel, W. W.; Jones, W. D. "Formation of 5-Membered Metallacycles at iPrPCPIr by C–H, O–H, and C–CO Bond Cleavage", Polyhedron, 2016, 116, 38-46.
(DOI: /10.1016/j.poly.2016.03.018)

195. Dinh, L. V.; Li, B.; Kumar, A.; Schinski, W.; Field, K. D.; Kuperman, A.; Celik, F. E.; Goldman, A. S. "Alkyl-Aryl Coupling Catalyzed by Tandem Systems of Pincer-Ligated Iridium Complexes and Zeolites", ACS Catal., 2016, 6, 2836-2841.
(DOI: 10.1021/acscatal.6b00149)

194. Brewster, T.P.; Rezayee, N.M.; Culakova, Z.; Sanford, M.S.; Goldberg, K.I., “Base Free Iridium-Catalyzed Hydrogenation of Esters and Lactones”, ACS Catal., 2016, 6, 3113-3117.
(DOI: 10.1021/acscatal.6b00263)

193. Cook, A. K.; Schimler, S. D.; Matzger, A. J.; Sanford, M. S. "Catalyst-controlled Selectivity in the C–H Borylation of Methane and Ethane", Science, 2016, 351, 1421-1424.
(DOI: 10.1126/science.aad9289)

192. Walden, A. G.; Kumar, A.; Lease, N.; Goldman, A. S.; Miller, A. J. M. " Electrochemical and Chemical Routes to Hydride Loss from an Iridium Dihydride", Dalton Trans., 2016, 45, 9766-9769.
(DOI: 10.1039/C6DT00522E)

191. Sues, P. E.; John, J. M.; Schrock, R. R.; Muller, P. "Molybdenum and Tungsten Alkylidene and Metallacyclobutane Complexes That Contain a Dianionic Biphenolate Pincer Ligand",  Organometallics,  2016, 35, 758-761.
(DOI:10.1021/acs.organomet.5b00976)

190. Xu, R.; Chakraborty, S.; Bellows, S. M.; Yuan, H.; Cundari, T. R.; Jones, W. D. " Iron-Catalyzed Homogeneous Hydrogenation of Alkenes under Mild Conditions by a Stepwise, Bifunctional Mechanism", ACS Catal., 2016, 6, 2127-2135.
(DOI: 10.1021/acscatal.5b02674)

189. Gallo, J. M. R.; Alamillo, R.; Dumesic, J. A. "Acid-Functionalized Mesoporous Carbons for the Continuous Production of 5-Hydroxymethylfurfural", J. Mol. Catal. A: Chem., 2016, 422, 13-17.
(DOI: 10.1016/j.molcata.2016.01.005)

188. Chen, Y.; Choi, S.; Thompson, L. T. "Low Temperature CO2 Hydrogenation to Alcohols and Hydrocarbons over Mo2C Supported Metal Catalysts", J. Catal., 2016, 343, 147-156.
(DOI: 10.1016/j.jcat.2016.01.016)

187. Bezier, D.; Guan, C.; Krogh-Jespersen, K.; Goldman, A. S.; Brookhart, M. "Experimental and Computational Study of Alkane Dehydrogenation Catalyzed by a Carbazolide-Based Rhodium PNP Pincer Complex", Chem. Sci., 2016, 7, 2579-2586.
(DOI: 10.1039/C5SC04794C)

186. Pitman, C. L.; Brereton, K. R.; Miller, A. J. M. "Aqueous Hydricity of Late Metal Catalysts as a Continuum Tuned by Ligands and the Medium"  J. Am. Chem. Soc., 2016, 138, 2252-2260.
(DOI: 10.1021/jacs.5b12363)

185. Kulkarni, A.; Kumar, A.; Goldman, A. S.; Celik, F. E. "Selectivity for Dimers in Pentene Oligomerization over Acid Zeolites", Catalysis Commun., 2016, 75, 98-102.
(DOI: 10.1016/j.catcom.2015.11.012)

184. Wang, D. Y.; Choliy, Y.; Haibach, M. C.; Hartwig, J. F.; Krogh-Jespersen, K.; Goldman, A. S. "Assessment of the Electronic Factors Determining the Thermodynamics of ‘Oxidative Addition’ of C-H and N-H Bonds to Ir(I) Complexes"  J. Am. Chem. Soc.,  2016, 138, 149-163.
(DOI: 10.1021/jacs.5b09522)
183. Bolig, A. D.; Lyons, T. W.; DiSalvo, D. T.; Brookhart, M. "Intramolecular Hydrogen Transfer Reactions Catalyzed by Pentamethylcyclopentadienyl Rhodium and Cobalt Olefin Complexes: Mechanistic Studies", Polyhedron, 2016, 103, 51-57. 
(DOI:10.1016/j.poly.2015.07.076)
182. Liu, Y.; Mellmer, M. A.; Alonso, D. M.; Dumesic, J. A. " Effects of Water on the Copper-Catalyzed Conversion of Hydroxymethylfurfural in Tetrahydrofuran", ChemSusChem, 2015, 8, 3983-3986. 
(DOI:10.1002/cssc.201501122)
181. Chakraborty, S.; Piszel, P.; Brennessel, W. W.; Jones, W. D. "A Single Nickel Catalyst for the Acceptorless Dehydrogenation of Alcohols and Hydrogenation of Carbonyl Compounds", Organometallics, 2015, 34, 5203-5206.
(DOI:10.1021/acs.organomet.5b00824)
180. Chen, Y.; Choi, S.; Thompson, L. T. "Ethyl Formate Hydrogenolysis over Mo2C-Based Catalysts: Towards Methanol Synthesis from CO/CO2 Hydrogenation", Catal. Today, 2015, 259, 285-291.
(DOI:10.1016/j.cattod.2015.08.021)
179. Chakraborty, S.; Piszel, P. E.; Hayes, C. E.; Baker, R. T.; Jones, W. D. "Highly Selective Formation of n-Butanol from Ethanol through the Guerbet Process: A Tandem Catalytic Approach", J. Am. Chem. Soc., 2015, 137, 14264-14267. 
(DOI:10.1021/jacs.5b10257)
178. Wyvratt, B. M.; Gaudet, J. R.; Thompson, L. T. "Effects of Passivation on Synthesis, Structure and Composition of Molybdenum Carbide Supported Platinum Water-Gas Shift Catalysts", J. Catal., 2015, 330, 280-287.
(DOI:10.1016/j.jcat.2015.07.023)
177. Xu, R.; Chakraborty, S.; Yuan, H.; Jones, W. D. "Acceptorless, Reversible Dehydrogenation and Hydrogenation of N-heterocycles with a Cobalt Pincer Catalyst", ACS Catalysis, 2015, 5, 6350-6354.
(DOI:10.1021/acscatal.5b02002)
176. Lyons, T. W.; Bezier, D.; Brookhart, M. "Iridium Pincer-Catalyzed Dehydrogenation of Ethers Featuring Ethylene as the Hydrogen Acceptor", Organometallics, 2015, 34, 4058-4062.
(DOI:10.1021/acs.organomet.5b00501)
175. Bellows, S. M.; Cundari, T. R.; Jones, W. D. "Methane Is the Best Substrate for C(sp3)–H Activation with Cp*(PMe3)Co(Me)(OTf): A Density Functional Theory Study",Organometallics, 2015, 34, 4032-4038.
(DOI: 10.1021/acs.organomet.5b00452)
174. Kumar, A.; Zhou, T.; Emge, T. J.; Zhuo, G.; Mironov, O.; Saxton, R. J.; Krogh-Jespersen, K.; Goldman, A. S. "Dehydrogenation of n-Alkanes by Solid-Phase Molecular Pincer-Iridium Catalysts. High Yields of α-Olefin Product", J. Am. Chem. Soc., 2015, 137, 9894-9911.
(DOI: 10.1021/jacs.5b05313)
173. Hanson, S. K.; Baker, R. T. "Knocking on Wood: Base Metal Complexes as Catalysts for Selective Oxidation of Lignin Models and Extracts", Acc. Chem. Res., 2015, 48, 2037-2048.
(DOI: 10.1021/acs.accounts.5b00104)
172. Denard, C. A.; Bartlett, M. J.; Wang, Y.; Lu, L.; Hartwig, J. F.; Zhao, H. "Development of a One- Pot Tandem Reaction Combining Ruthenium-catalyzed Alkene Metathesis and Enantioselective Enzymatic Oxidation to Produce Aryl Epoxides", ACS Catal., 2015, 5, 3817-3822.
(DOI: 10.1021/acscatal.5b00533)
171. Kovach, J.; Brennessel, W. W.; Jones, W. J. "Electrophilic C-H Activation of Benzene with a Shilov-inspired Rhodium(III) Diimine Complex", J. Organomet. Chem. 2015, 793, 192-199.
(DOI: 10.1016/j.jorganchem.2015.05.005)
170. Xiao, H.; Z. Bao, Z.; Zhao, H. “High Throughput Screening and Selection Methods for Directed Enzyme Evolution” Ind. Eng. Chem. Res., 2015, 54, 4011−4020.
(DOI: 10.1021/ie503060a)
169. Zhou, M.; Goldman, A. S., "Chlorination of (Phebox)Ir(mesityl)(OAc) by ThionylChloride", Molecules, 2015, 20, 10122-10130.
(DOI: 10.3390/molecules200610122)
168. Fujita, E.; Goldman, A. S. "Preface for Small-Molecule Activation: Carbon-Containing Fuels", Inorg. Chem., 2015, 54, 5040-5042.
(DOI: 10.1021/acs.inorgchem.5b00790)
167. Zhou, M.; Johnson, S. I.; Gao, Y.; Emge, T. J.; Nielsen, R. J.; Goddard, W. A., III; Goldman, A. S. "Activation and Oxidation of Mesitylene C–H Bonds by (Phebox)Iridium(III) Complexes", Organometallics, 2015, 34, 2879-2888.
(DOI: 10.1021/acs.organomet.5b00200)
166. Goldberg, J. M.; Wong, G. W.; Brastow, K. E.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. "The Importance of Steric Factors in Iridium Pincer Complexes", Organometallics, 2015, 34, 753-762.
(DOI: 10.1021/om501166w)
165. Chen, Y.; Choi, S.; Thompson, L. T. "Low-Temperature CO2 Hydrogenation to Liquid Products via a Heterogeneous Cascade Catalytic System", ACS Catal., 2015, 5, 1717-1725.
(DOI: 10.1021/cs501656x)
164. Cook, A. K.; Sanford, M. S. "Mechanism of the Palladium-Catalyzed Arene C-H Acetoxylation: A Comparison of Catalysts and Ligand Effects", J. Am. Chem. Soc., 2015, 137, 3109-3118.
(DOI: 10.1021/jacs.5b00238)
163. Lehman, M. C.; Pahls, D. R.; Meredith, J. M.; Sommer, R. D.; Heinekey, D. M.; Cundari, T. R.; Ison, E. A. "Oxyfunctionalization with Cp*IrIII(NHC)(Me)(Cl) with O2: Identification of a Rare Bimetallic IrIV µ-Oxo Intermediate", J. Am. Chem. Soc., 2015, 137, 3574-3584.
(DOI: 10.1021/ja512905t)
162. Rezayee, N. M.; Huff, C. A.; Sanford, M. S. "Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol", J. Am. Chem. Soc., 2015, 137, 1028-1031.
(DOI: 10.1021/ja511329m)
161. Denard, D. A.; Ren, H.; Zhao, H. "Improving and Repurposing Biocatalysts via Directed Evolution", Curr. Opin. Chem. Biol., 2015, 25, 55-64.
(DOI: 10.1016/j.cbpa.2014.12.036)
160. Frasco, D. A.; Sommer, R. D.; Ison, E. A. "ortho-C–H Activation of Thiobenzoic Acid: Synthesis, Characterization, and Reactivity of Iridium Thiobenzoate Complexes", Organometallics, 2015, 34, 275-279.
(DOI: 10.1021/om501115u)
159. Laviska, D. A.; Field, K. D.; Sparks, S. M.; Goldman, A. S. "The LEEDAR Program: Learning Enhanced through Experimental Design and Analysis with Rutgers", in Service Learning and Environmental Chemistry: Relevant Connections; Roberts-Kirchhoff, E. S.; Mio, M. J.; Benvenuto, M. A., Eds.; ACS Symposium Series 1177; American Chemical Society: Washington, DC, 2014, pp 209-228.
(DOI: 10.1021/bk-2014-1177.ch012)
158. Pahls, D. R.; Allen, K. E.; Goldberg, K. I.; Cundari, T. R. "Understanding the Effect of Ancillary Ligands on Concerted Metalation–Deprotonation by (dmPhebox)Ir(OAc)2(H2O) Complexes: A DFT Study", Organometallics, 2014, 33, 6413-6419.
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70. Ateşin, T. A.; Kundu, S.; Skugrud, K.; Lai, K.; Swartz, B. D.; Jones, W. D. "Predicting Selectivity in Oxidative Addition of C-S Bonds of Substituted Thiophenes to Pt(0) Fragment: Experimental and Theoretical Study", Organometallics, 2011, 30, 4578-4588. 
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69. Emmert, M. H.; Cook, A. K.; Xie, Y. J.; Sanford, M. S. "Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected C-H Oxygenation of Arenes", Angew. Chem. Int. Ed., 2011, 50, 9409-9412.
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68. Engelman, K. L.; Feng, Y.; Ison, E. A. "C-H Bond Functionalization of Benzoic Acid: Catalytic Synthesis of 2-Hydroxy-6H-benzo[c]chromen-6-ones using (Cp*IrCl2)2", Organometallics, 2011, 30, 4572-4577.
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67. Matson, T. D.; Barta, K.; Iretskii, A. V.; Ford, P. C.  "One-Pot Catalytic Conversion of Cellulose and of Woody Biomass Solids to Liquid Fuels", J. Am. Chem. Soc. 2011, 133, 14090-14097.
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66. Choi, J.; Wang, D. Y.; Kundu, S.; Choliy, Y.; Emge, T. J.; Krogh-Jespersen, K.; Goldman, A. S. "Net Oxidative Additional of C(sp3)-F Bonds to Iridium via Initial C-H Bond Activation", Science, 2011, 332, 1545-1548.
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65. Lanci, M. P.; Remy, M. S.; Lao, D. B.; Sanford, M. S.; Mayer, J. M. "Modulating Sterics in Trimethylplatinum(IV) Diimine Complexes To Achieve C-C Bond-Forming Reductive Elimination", Organometallics, 2011, 30, 3704-3707.
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44. Ahuja, R.; Punji, B.; Findlater, M.; Supplee, C.; Schinski, W.; Brookhart, M.; Goldman, A. S. "Catalytic Dehydroaromatization of n-Alkanes by Pincer-Ligated Iridium Complexes", Nature Chem., 2011, 3, 167-171.
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43. Tabane, T.; Evans, M. E.; Brennessel, W. W.; Jones, W. D. "C-H and C-CN Bond Activation of Acetonitrile and Succinonitrile by [Tp'Rh(PR3)]", Organometallics, 2011, 30, 834-843.
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40. Becker, R.; Jones, W. D. "Cobalt and Nickel Catalyzed Reactions Involving C-H and C-N Activation Reactions", in Catalysis Without Precious Metals, Bullock. R. M., Ed., Wiley VCH Publishers, 2010, Ch. 6, 143-164.
39. Hanson, S. K.; Baker, R. T.; Gordon, J. C.; Scott, B. L.; Silks, L. A. "Pete"; Thorn, D. L., "Mechanism of Alcohol Oxidation by Dipicolinate Vanadium(V): Unexpected Role of Pyridine", J. Am. Chem. Soc., 2010, 132, 17804-17816.
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34. Nair, N. U.; Zhao, H., "Selective reduction of xylose to xylitol from a mixture of hemicellulosic sugars", Metab. Eng , 2010, 12, 462-468.
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33. Barta, K.; Matson, T. D.; Fettig, M. L.; Scott, S. L.; Iretskii, A. V.; Ford, P. C., "Catalytic disassembly of an organosolv lignin via hydrogen transfer from supercritical methanol", Green Chemistry , 2010, 12, 1640-1647. (DOI:10.1039/C0GC00181C)
32. Emmert, M. H.; Gary, J. B.; Villalobos, J. M.; Sanford, M. S., "Platinum and Palladium Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation", Angew. Chem. Int. Ed. Eng., 2010, 49, 5884-5886.
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31. Feng, Y.; Jiang, B.; Boyle, P. A.; Ison, E. A., "Effect of Ancillary Ligands and Solvents on H/D Exchange Reactions Catalyzed by Cp*Ir Complexes", Organometallics, 2010, 29, 2857.
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30. Crisci, A. J.; Tucker, M. H.; Dumesic, J. A.; Scott, S. L., "Bifunctional Solid Catalysts for the Selective Conversion of Fructose to 5-Hydroxymethylfurfural", Topics in Catalysis, 2010, 53, 1185-1192.
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29. Hanson, S. K.; Baker, R. T.; Gordon, J. C.; Scott, B. L.; Thorn, D. L., "Aerobic Oxidation of Lignin Models Using a Base Metal Vanadium Catalyst", Inorg. Chem., 2010, 49, 5611-5618.
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28. Punji, B.; Emge, T. J.; Goldman, A. S., "A Highly Stable Adamantyl-Substituted Pincer-Ligated Iridium Catalyst for Alkane Dehydrogenation", Organometallics, 2010, 29, 2702-2709.
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27. Huang, Z.; White, P. S.; Brookhart, M., "Ligand Exchanges and Selective Catalytic Hydrogenation in Molecular Single Crystals", Nature, 2010, 465, 598-601.
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26. Findlater, M.; Bernskoetter, W. H.; Brookhart, M., "Proton-Catalyzed Hydrogenation of a d8 IrI Complex Yields a trans IrIII Dihydride", J. Am. Chem. Soc., 2010, 132, 4534-4535.
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25. Remy, M. S.; Cundari, T. R.; Sanford, M. S., "Computational and Experimental Studies of Methyl Group Exchange between Palladium(II) Centers", Organometallics, 2010, 29, 1522-1525.
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24. Tan, Y.; Hartwig, J. F., "Palladium-Catalyzed Amination of Aromatic C-H Bonds with Oxime Esters", J. Am. Chem. Soc., 2010, 132, 3676-3677.
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23. Ke, Z.; Cundari, T.R., "Palladium-Catalyzed C-H Activation/C-N Bond Formation Reactions: DFT Study of Reaction Mechanisms and Reactive Intermediates", Organometallics, 2010, 29, 821-834.
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22. Huang, Z.; Rolfe, E.; Carson, E. C.; Brookhart, M.; Goldman, A. S.; El-Khalafy, S. H.; MacArthur, A. H. R. , "Efficient Heterogeneous Dual Catalyst Systems for Alkane Metathesis", Adv. Synth. Catal., 2010, 352, 125-135
(DOI: 10.1002/adsc.200900539)
21. Marquard, S. L.; Rosenfeld, D. C.; Hartwig, J. F., "C(sp3)-N Bond-Forming Reductive Elimination of Amines: Reactions of Bisphosphine-Ligated Benzylpalladium(II) Diarylamido Complexes", Angew. Chem. Int. Ed. Eng., 2010, 49, 793-796.
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20. Villalobos, J. M.; Hickman, A. J.; Sanford, M. S., "Platinum(II) Complexes Containing Quaternized Nitrogen Ligands: Synthesis, Stability, and Evaluation as Catalysts for Methane and Benzene H/D Exchange", Organometallics, 2010, 29, 257-262.
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19. Hickman, A.; Villalobos, J. A.; Sanford, M. S., "A Quantitative Method to Assay Platinum Catalysts for Benzene H/D Exchange", Organometallics, 2009, 28, 5316-5322.
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18. Lanci, M. P.; Remy, M. S.; Kaminsky, W.; Mayer, J. M.; Sanford, M. S., "Oxidatively Induced Reductive Elimination from (tBu2bpy)Pd(Me)2: Palladium(IV) Intermediates in a One Electron Oxidation Reaction", J. Am. Chem. Soc., 2009, 131, 15618-15620.
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17. Wesley H. Bernskoetter, Cynthia K. Schauer, Karen I. Goldberg, and Maurice Brookhart, "Characterization of a Rhodium(I) σ-Methane Complex in Solution", Science, 2009, 326, 553-556.
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16. Kundu, S.; Choliy, Y.; Zhuo, G.; Ahuja, R.; Emge, T. J.; Warmuth, R.; Brookhart, M.; Krogh-Jespersen, K.; Goldman, A. S. "Rational Design and Synthesis of Highly Active Pincer-Iridium Catalysts for Alkane Dehydrogenation", Organometallics, 2009, 28, 5432-5444.
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15. Bernskoetter, W. H.; Hanson, S. K.; Buzak, S. K.; Davis, Z.; White, P. S.; Swartz, R.; Goldberg, K. I.; Brookhart, M. "Investigations of Iridium Mediated Reversible C-H Bond Cleavage: Characterization of a 16-Electron Iridium(III) Methyl Hydride Complex", J. Am. Chem. Soc., 2009, 28, 3546-3551.
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14. Meredith, J. M.; Goldberg, K. I.; Kaminsky, W.; Heinekey, D. M. "Dinuclear Iridium Complexes Containing Cp* and Carbonyl Ligands: Synthesis, Structure and Reactivity" Organometallics, 2009, 28, 3546-3551.
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13. Goldman, A. S.; Brookhart, M.; Huang, Z.; Krogh-Jespersen, K.; Kundu, S.; Scott, S. L. "Transition-metal-based catalytic systems for the dehydrogenation and metathesis of alkanes. Solution-phase and solid-supported iridium-based pincer catalysts." Prepr. Symp. - Am. Chem. Soc., Div. Fuel Chem., 2009, 54, 213-215.
12. Ter Horst, M.; Urbin, S.; Burton, R.; McMillan, C. "Using proton nuclear magnetic resonance as a rapid response research tool for methyl ester characterization of biodiesel", Lipid Technology, 2009, 21, 39-41.
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11. Look, J. L.; Wick, D. D.; Mayer, J. M.; Goldberg, K. I. "Autoxidation of Platinum(IV) Hydrocarbyl Hydride Complexes to Form Platinum(IV) Hydrocarbyl Hydroperoxide Complexes", Inorg. Chem., 2009, 48, 1356-1369.
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10. Huang, Z.; Brookhart, M.; Goldman, A. S.; Kundu, S.; Ray, A.; Scott, S. L.; Vicente, B. C. "Highly active and recyclable heterogeneous iridium pincer catalysts for transfer dehydrogenation of alkanes" Adv. Synth. Catal., 2009, 351, 188-206.
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9. Macala, G. S.; Matson, T. D.; Johnson, C. L.; Lewis, R.; Iretskii, A. V.; Ford, P. C. "Hydrogen Transfer from Super-critical Methanol over a Solid Base Catalysts. A Model for Lignin Depolymerization" ChemSusChem, 2009, 2, 215-217.
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8. Hanson, S. K.; Baker, R. T.; Gordon, J. C.; Scott, B. L.; Sutton, A. D.; Thorn, D. L. "Aerobic Oxidation of Pinacol by Vanadium(V) Dipicolinate Complexes: Evidence for Reduction to Vanadium(III)" J. Am. Chem. Soc., 2009, 131 (2), 428-429.
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7. Bailey, B. C.; Schrock, R. R.; Kundu, S.; Goldman, A. S.; Huang, Z.; Brookhart, M. "Evaluation of Molybdenum and Tungsten Metathesis Catalysts for Homogeneous Tandem Alkane Metathesis", Organometallics, 2009, 28(1), 355-360.
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6. Macala, G. S.; Robertson, A. W.; Johnson, C. L.; Day, Z. B.; Lewis, R. S.; White, M. G.; Iretskii, A. V.; Ford, P. C. "Transesterification Catalysts from Iron Doped Hydrotalcite-like Precursors: Solid Bases for Biodiesel Production" Catalysis Letters, 2008, 122(3-4), 205-209.
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4. Williams, D. B.; Kaminsky, W.; Mayer, J. M.; Goldberg, K. I., "Reactions of Iridium Hydride Pincer Complexes with Dioxygen: New Peroxo Complexes and Reversible O2 Binding" ChemComm., 2008, 35, 4195-4197.
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3. Foley, N. A.; Ke, Z.; Gunnoe, T. B.; Cundari, T. R.; Petersen, J. L. "Aromatic C-H Activation and Catalytic Hydrophenylation of Ethylene by TpRu{P(OCH2)3CEt}(NCMe)Ph" Organometallics, 2008, 27(13), 3007-3017.
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1. Ahuja, R.; Kundu, S.; Goldman, A. S.; Brookhart, M.; Vicente, B. C.; Scott, S. L. "Catalytic Ring Expansion, Contraction, and Metathesis-Polymerization of Cycloalkanes" ChemComm., 2008, 253-255.
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CATSB (Phase I) Publications:

1. Kloek, Susan M.; Heinekey, D. Michael; Goldberg, Karen I.; "C-H bond activation by rhodium(I) hydroxide and phenoxide complexes" Angewandte Chemie, International Edition, 2007, 46(25), 4736-4738
(DOI: 10.1002/anie.200700270)
2. Kloek, Susan M.; Goldberg, Karen I. "Competitive C-H Bond Activation and β-Hydride Elimination at Platinum(II)" J. Am. Chem. Soc., 2007, 129 (12), 3460-3461
(DOI: 10.1021/ja0669629)
3. X. Zhang; T. J. Emge; A. S. Goldman, "Selective Cleavage of the C-C Bond of Aminoethyl Groups, via a Multistep Pathway, by a Pincer Iridium Complex", J. Am. Chem. Soc., 2005, 127, 8250
(DOI: 10.1021/ja051300p)
4. Alan S. Goldman; Amy H. Roy; Zheng Huang; Ritu Ahuja; William Schinski; Maurice Brookhart, "Catalytic Alkane Metathesis by Tandem Alkane-Dehydrogenation-Olefin-Metathesis", Science, 2006, 312, 257
(DOI: 10.1126/science.1123787)
5. Susan M. Kloek; D. Michael Heinekey; Karen I. Goldberg, "Stereoselective Decarbonylation of Methanol to Form a Stable Iridium(III) Trans-Dihydride Complex", Organometallics, 2006, 25, 3007
(DOI: 10.1021/om051098z)
6. Devon C. Rosenfeld; Shashank Shekhar; Akihiro Takemiya; Masaru Utsunomiya; John F. Hartwig*, "Hydroamination and Hydroalkoxylation Catalyzed by Triflic Acid. Parallels to Reactions Initiated with Metal-Triflates", Org. Lett., 2006, 8 (19), 4179-4182
(DOI: 10.1021/ol061174+)
7. Inigo Göttker-Schnetmann; D. M. Heinekey; Maurice Brookhart, "Temperature and Solvent Dependent Binding of Dihydrogen in Iridium Pincer Complexes."  J. Am. Chem. Soc., 2006, 128, 17115-17119
(DOI: 10.1021/ja065854j)

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This work was supported by NSF under the CCI Center for Enabling New Technologies Through Catalysis, CHE-1205189. Any opinions, findings, and conclusions or recommendations expressed here are those of the authors and do not necessarily reflect the views of the National Science Foundation (NSF).

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